The influences of reaction time, temperature and NH4NO3 concentration on the reaction of solid β-UO
3 with aqueous NH
4NO
3 were experimentally studied. Both type I(UO
3•2H
2O) and type II(3UO
3-NH
3-5H
2O) uranyl compounds were observed in the X-ray diagrams of reaction product. High temperature (80°C) and long reaction time (2 h) favor the formation of type II uranyl compounds and generation of uranyl nitrate. Based on the experimental results, two possible models were proposed. The model that assumed pseudohomogeneous reactions conforms to the experimental data better than the model that assumed noncatalytical solid-fluid heterogeneous chemical reaction. The dependence of uranyl nitrate generation rate on reaction time, temperature and NH
4NO
3 concentration can be calculated from the pseudohomogeneous reaction model.
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