Accelerated short-term leach tests in a laboratory are neccessary in order to estimate, with reasonable accuracy, the long-term leaching behavior of high-level waste glass. In the present study, static leach tests of an SRL-165 high-level waste glass were carried out in deionized water at two different glass-surface-area to solution-volume ratios (SA/V-ratio), namely 0.85 and 0.079 cm
-1 at 90°C, and 0.85 cm
-1 at 40°C.
First, an equation was examined which related Si-concentrations with time, temperature and SA/V-ratio under the present static conditions. The parameter determined at 90°C, 0.85 cm
-1 can be used to calculate the Si-concentration at 40°C, 0.85 cm
-1. Second, at the low SA/V-ratio of 0.079 cm
-1, the concentrations of Ca and Mg in the leachates peaked and then decreased a little. The equation used above does not explain the variation of the concentrations of Ca and Mg at a low SA/V-ratio. The precipitation of Ca and Mg onto the glass surface is probably caused by the adsorption efficiency of the surface layer or the formation of crystalline materials at the low SA/V-ratio of 0.079 cm
-1. Third, the in-depth profiles of some elements obtained by secondary ion mass spectroscopy (SIMS) were qualitatively in agreement with the results of solution analyses. This indicates the particular usefulness of SIMS for analyzing leaching behavior of the glass in in-situ burial studies where solution analyses are often impractical.
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