Formation conditions, compositions and structures of precipitates or "the third phase" were systematically examined in the systems of Zr and radiation depleted products of TBP, such as HDBP, H
2MBP, H
3PO
4, by means of elemental analysis, X-ray diffraction, infrared spectra and
1H-NMR. It was confirmed that one of the most important origins for the third phase is a complexation between Zr ion and the depleted products of TBP. Followings were also elucidated :
(1) When the depleted products co-exist with each other, the cooperative effects on the precipitate formation appear in low acid solutions.
(2) Precipitate formation depends on the mole ratio of HDBP/Zr. The amount of precipitate reaches the maximum at the mole ratio of approximately 2 and decreases with increasing concentration of HDBP and finally disappears at approximately 10.
(3) Precipitate formed at the mole ratio of approximately 2 has the chemical formula, Zr(NO
3)
2(HDBP)
2(OH)
2.
(4) Precipitates of the Zr-H
2MBP system begin to appear at the concentration of H
2MBP in one order of magnitude smaller than that of HDBP in Zr-HDBP system.
(5) Precipitates of Zr-H
2MBP system have no NO
3 ion and a basic structure of Zr (HMBP)
2(OH)
2 with an interlayer distance of 16 Å.
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