The UC-UN solid solution, UC
1-xN
x, exists stably in monophase within a certain range of nitro-gen pressure at constant temperature. At the upper limit of this range, UC
1-xN
x coexists with UC
2 or with carbon, and it precipitates metallic uranium at the lower limit which corresponds to the de-composition pressure of UC
1-xN
x.
In order to measure the decomposition temperature of UC
1-xN
x with given x under constant nitrogen pressure, it is necessary to heat UC
1-xN
x without changing its composition, at a constant pressure.
In the present work, preliminary considerations have been given to change in composition. Ex-periments were also performed in which the solid solution was heated at a rate of 200°C/min under different nitrogen pressures.
From the results, it is concluded that there exists a temperature range within which the value of x in UC
1-xN
x is maintained constant when the nitrogen pressure is fixed.
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