油化学
Online ISSN : 1884-2003
ISSN-L : 0513-398X
34 巻 , 3 号
選択された号の論文の9件中1~9を表示しています
  • 大場 健吉, 武井 玲子
    1985 年 34 巻 3 号 p. 161-170
    発行日: 1985/03/20
    公開日: 2010/02/19
    ジャーナル フリー
  • 西村 正人
    1985 年 34 巻 3 号 p. 171-177
    発行日: 1985/03/20
    公開日: 2010/02/19
    ジャーナル フリー
  • 平田 博文, Alemka KISIC, John BRABSON, George J. SCHROEPFER JR
    1985 年 34 巻 3 号 p. 178-183
    発行日: 1985/03/20
    公開日: 2009/11/10
    ジャーナル フリー
    スフィンゴシン塩基の分析は一般にN-アセチルO-TMS誘導体としてGLCやGLC-MSによって行われるが, その化合物の簡便な調製法は今までに報告されていない。
    本報ではスフィンゴシン塩基の準アシルO-TMS誘導体の簡易調製法について検討した。スフィンゴシン塩基とHMDS+TMCS/ピリジンとの反応から生ずるO-TMS誘導体と酸無水物とを反応させると目的のN-アシル化が起こり, N-アシルO-TMS化合物が得られた。BSA/アセトニトリルとの反応から生ずるN, O-TMS体は, N-TMS基がアミノ基の保護基として作用するため, 酸無水物とは反応しなかった。上記のN-アシルO-TMS化反応について数種のスフィンゴ塩基について検討したところ, すべての場合について起こることが認められた。生成物の構造はGLC, GLC-MSから決定した。合成したCn-ジヒドロスフィンゴシン (n=12, 14, 16) をN-アシルO-TMS体とし, そのerythro/threo比を求めたところ, 従来法で求めた結果 (BSAを用い, N, O-TMS体としGLCで定量) と一致した。本報の特色は, スフィンゴシン塩基のNアシルO-TMS体が簡便に調製でき, かつ, 短時間の反応で行うことができる点にある。しかも, GLC-MSの分析の際, スフィンゴシン塩基のN-アシル体を別途合成することなく, O-TMS体とN-アシルO-TMS体両方の測定ができる利点がある。
  • 山岡 正和
    1985 年 34 巻 3 号 p. 184-186
    発行日: 1985/03/20
    公開日: 2009/11/10
    ジャーナル フリー
    α-トコトリエニルアセタート (I), α-トコフェリルァセタート (II), 及びα-トコトリエノール (III) の酸化によるケミルミネッセンスを, 酸素気流下暗所で測定した。Iは60℃では発光しないが, 100℃では発光した。同温度でも五, 皿は発光しなかった。これらの事から, 1が60℃では100℃の時に比べて酸化されにくいこと, 及び皿の不飽和な側鎖とフェノール性ヒドロキシル基との間に相互作用のあることが示された。
  • 日下 兵爾, 永野 誠司, 太田 静行
    1985 年 34 巻 3 号 p. 187-190
    発行日: 1985/03/20
    公開日: 2009/11/10
    ジャーナル フリー
    In determining the mechanism by which silicone oil (SO) suppresses the thermal deterioration of a frying oil, the influence of SO on the convection of soybean oil was examined. In this experiment, two kinds of SO were used : dimethyl polysiloxane (SO-DMPS) which very effectively suppresses the thermal deterioration of frying oils and methyl phenyl polysiloxane (SO-Phenyl-S) which has no such effect.
    To observe the degree of convection, the following method was used. One drop of soybean oil colored with Sudan III was added to soybean oil with or without SO heated at 150°C, 180°C and 210°C.The life span of this pigment, i.e. the time between its addition and disappearance, was measured.
    This pigment existed in oil with SO-DMPS for a longer period of time than in oil without SO. The time in oil with SO-Phenyl-S was the same as that in oil without SO.
    These observations demonstrate that SO effectively slowed down the convection current of frying oil. The influence of SO on convection current of frying oil seems to be a function of SO.
  • 矢上 一夫, 堀田 修, 中川 真弓, 山田 仁穂
    1985 年 34 巻 3 号 p. 191-197
    発行日: 1985/03/20
    公開日: 2009/11/10
    ジャーナル フリー
    Radical telomerization was carried out using vinylpyrrolidon and methyl acrylate as monomers and 1-dodecanthiol. Benzene was used as the solvent and α, α'-azobisisobutyronitrile, as the initiator. The synthesized telomers (Ls-VPr-MA series) were treated with alkaline solvent to give various saponificated products. The cmc and chelating values of these telomers increased and lime soap dispersion power, orange OT solubilization and anti-redeposition ability decreased inversely with the degree of saponification. Surface tension and CaCO3 dispersion ability attained a maximum at 50 mol% saponification.
    The detergency of the detergent made from Ls-VPr-MA series telomers, builders and LAS or soap decreased as the degree of saponification increased. This tendency was particularly pronounced for the soap detergent system and polyester test fabric. In regard to the effects of the functional group of the telomers on detergency, the pyrrolidone and methoxycarbonyl group combination was considered far superior to individual carboxyl, carbamoyl, and pyrrolidone groups or their combination. The Ls-VPr-MA-Na telomers showed the strongest detergency effect at the degree of polimerization (DP) 10.
    Detergency of the soap containing Ls-VPr-MA telomers was superior to the commercial lime soap dispersion agent, and Ls-VPr-MA telomers was effective when present at 5, 10% in the detergent.
  • 滝田 八広
    1985 年 34 巻 3 号 p. 198-201
    発行日: 1985/03/20
    公開日: 2009/11/10
    ジャーナル フリー
    Changes in the effects of linear alkylbenzenesulfonate (LAS) on the growth of sporelings of Porphyra yezoensis were studied during biodegradation in sea water to determine its compatibility with aquatic organisms. The bioassay results showed inhibition by commercial LAS of the growth of sporelings to decrease on biodegradation in sea water and the longer alkyl chain homologues and outer phenyl isomers of LAS to effect the degree of toxicity toward sporeling growth.
    The results of the chemical analysis by GLC showed the toxic components in commercial LAS to decrease more rapidly than other components during biodegradation in sea water. The toxicity of commercial LAS toward aquatic organisms in sea water is considered to decrease when its effective components undergo biodegradation
  • 阿部 芳郎, 松村 秀一, 真子 義邦, 橋本 克夫, 三浦 健司, 酒井 要
    1985 年 34 巻 3 号 p. 202-205
    発行日: 1985/03/20
    公開日: 2009/11/10
    ジャーナル フリー
    Poly [(sodium acrylate) -co- (sodium vinyl sulfonate)] P (A-VS) with a no.-av. molecular weight (Mn) of 380026850 and poly (sodium vinylsulfonate) (PVS) with a Mn of 5040 were prepared and their detergency building powers were examined. Their sequestering power for Ca2+ and dispersing power for MnO2 were determined and compared with the corresponding properties for oligomeric poly (sodium acrylate), tripolyphosphate (STPP) and disodium 3-oxapentanedioate (ODA). The biodegra clability of the oligomers was also studied under aerobic conditions.
    Oligomeric P (A-VS) showed better detergency building performance than that of ODA, but was slightly inferior to those of STPP and oligomeric poly (sodium acrylate). Oligomeric P (A-VS) was more biodegradable than the corresponding sodium acrylate oligomer. Introduction of sulfonate groups to sodium acrylate oligomers promoted their biodegradability.
  • 田中 満
    1985 年 34 巻 3 号 p. 206-211
    発行日: 1985/03/20
    公開日: 2009/11/10
    ジャーナル フリー
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