Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
Volume 42 , Issue 9
Showing 1-8 articles out of 8 articles from the selected issue
  • Mitsuteru MASUDA, Hiroshi ODAKE, Kazuaki MIURA, Kenkichi OBA
    1993 Volume 42 Issue 9 Pages 643-648
    Published: September 20, 1993
    Released: October 16, 2009
    JOURNALS FREE ACCESS
    The biodegradability of 2-sulfonatofatty acid methylester (a-SFMe), an anionic surfactant recently developed for heavy-duty household detergents, was studied by the shake culture method, river die-away test and biochemical oxygen demand measurment method (MITI test).
    Biodegradation was followed by the methylene blue active substances (MBAS) analysis and/or dissolved organic carbon (DOC), or biochemical oxygen demand (BOD).
    The biodegradation of α-SFMe was found to start quickly, and then to proceed rapidly to ultimate degradation at sewage treatment plants and in natural river water.
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  • Mutsumi SUGITA, Chieko HAYATA, Taro HORI, Aki MORIKAWA, Sachiyo MIWA
    1993 Volume 42 Issue 9 Pages 649-655
    Published: September 20, 1993
    Released: October 16, 2009
    JOURNALS FREE ACCESS
    An antibody against Amino-CTH containing mannose, GlcNAcβ1-3 Manβ1-4 Glcβ1-Ceramide (ArOse3 Cer) isolated from the larvae of the green-bottle fly, Lucilia caesar, was purified by affinity chromatography from rabbit antiserum. The specificity of the antibody was verified by ELISA and TLC-immunostaining. It was found to bind to ArOse3Cer and ArOse3-sphingosine, and to a lesser extent to certain other compounds containing an N -acetylglucosamine residue at their termini, such as GlcNAcβ 1-3 Gal β1-4 Glcβ 1-Ceramide (Amino-CTH) and GlcNAcβ 1-2 Man α 1-3 Manβ1-4 Glcβ 1-Ceramide (MlOse4 Cer). This antibody was used to detect the natural hapten in crustacean glycolipids. The purified antibody reacted with a neutral glycosphingolipid in Euphausia superba (antarctic krill) and Macrobrachiurn nipponense (fresh-water shrimp), as indicated by TLC-immunostaining. The crustacean glycolipid antigen was isolated and characterized as GlcNAcβ1-3 Manβ 1-4 Glc-Ceramide. This is the first paper to demonstrate the presence of an Amino-CTH containing mannose in the crustacean. Cryostat sections of M. nipponense were examined to determine the distribution of ArOse3Cer with the purified antibody. Clear staining was observed in the green gland, esophagus and gills.
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  • Kouichi ASAKURA, Takatoshi SHIOTANI, Eitoshi HONDA, Shuichi MATSUMURA
    1993 Volume 42 Issue 9 Pages 656-660
    Published: September 20, 1993
    Released: October 16, 2009
    JOURNALS FREE ACCESS
    Phenolic oligomers directly linked to aromatic rings were prepared by horseradish peroxidase catalyzed oxidation of phenol derivatives by hydrogen peroxide. The phenols used were p-cresol, p-ethylphenol, p-s-butylphenol, p-t-butylphenol, p-methoxyphenol, p-nonylphenol, m-cresol, m-t-butyl-phenol, m-methoxyphenol, and 3, 4-xylenol. p-Nonylphenol and m-t-butylphenol were not polymerized by oxidation. Number-average molecular weights (Mn) of para alkyl substituted phenolic oligomers were about 800 and bulky substituted groups prevented decrease in the number of hydroxyl groups during polymerization. Mn of p-methoxyphenol oligomer was almost 1700. Meta substituted oligomers had lower Mn and a greater number of remaining hydroxyl groups (D.R.H.) than the corresponding para substituted phenol oligomers. Antioxidant effects of the phenolic oligomers on the autoxidation of lard were evaluated. Improvement of this effect for lard could hardly be detected by polymerization. That of the oligomers on the autoxidation of tetralin was much more pronounced than for the corresponding monomers, except for p-methoxyphenol. Higher reactivity of phenolic oligomers toward peroxyl radicals and the formation of stable phenoxyl radicals may possibly have been the cause for this. Phenolic oligomers having higher D.R.H. exhibited the better antioxidant effect. The antioxidant effects of meta substituted oligomers were greater than those of the corresponding para substituted oligomers.
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  • Takamitsu TAMURA, Masako FUJITSU, Kiyoharu ITOH
    1993 Volume 42 Issue 9 Pages 661-667
    Published: September 20, 1993
    Released: October 16, 2009
    JOURNALS FREE ACCESS
    Partial phase diagrams and microstructures were investigated in a one-phase microemulsion region of sodium oleate/monoalkyl poly (oxyalkylene) ethers/water ternary systems by conductivity, freezefracture electron microscopy and pulsed field gradient spin-echo (PGSE) NMR measurements. The influence of n-decane and glycerol trioleate on the ternary phase diagrams was also examined. Monomethyl, ethyl and butyl poly (oxyethylene) ethers and monobutyl ethers having both ethylene oxide (EO) and propylene oxide (PO) groups with different alkylene oxide chain length were used for this purpose. Although similar one phase microemulsion regions appeared in the monobutyl poly (oxyethylene) ether ternary systems, the microemulsion regions shrunk on increasing EO chain length by adding n-decane and glycerol trioleate. The introduction of PO groups at the terminal position of ethers had a spreading effect on the one phase region even in quaternary systems. Transition from water-in-oil to oil-in-water microemulsions through bicontinuous structures was found to occur with increase in water content.
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  • Hikoji YOSHIMURA
    1993 Volume 42 Issue 9 Pages 668-674
    Published: September 20, 1993
    Released: October 16, 2009
    JOURNALS FREE ACCESS
    8- or 9- [2- (perfluorooctyl) ethoxy] -tricyclo [5. 2. 1.02' 6] deca- 3- en (1) was synthesized by the reaction of 2- (perfluorooctyl) ethanol with dicyclopentadiene in the presence of boron trifluo-ride- ethyl ether complex. The reaction rate exceeded that of the linear hydrocarbon alcohol with dicyclopentadiene. At the start of liquid phase oxygen oxidation, radicals were formed by the abstraction of hydrogen at the allyl position of (1) in the presence of azobis (isobutyronitrile), and peroxy radicals were subsequently produced by oxygen attack. The peroxy radical produced hydroperoxide by hydrogen abstraction in an intermolecular manner. At above a concentration of 10 % hydroperoxide, was converted to the corresponding hydroxide and ketone. The activation energy of hydroperoxide formation in neat was 20.6 kcal mol-1. Neither the addition of the peroxy radical to a double bond nor its coupling could be detected.
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  • Hikoji YOSHIMURA
    1993 Volume 42 Issue 9 Pages 675-679
    Published: September 20, 1993
    Released: October 16, 2009
    JOURNALS FREE ACCESS
    A study was made of the liquid phase oxygen oxidation of 8- or 9- [2- (perfluorooctyl) ethoxy] -tricyclo [5. 2. 1.02, 6] deca-3-en, active catalytic species, reaction behavior and components of products. The catalysts used were radical forming type : azobis (isobutyronitrile) and benzoyl peroxide, and transition metal salt type : Co-naphthenate and Mn- naphthenate. All reactions were carried out with oxygen bubbling in a xylene solution.
    Using radical forming catalysis, practically hydroperoxide alone was produced upto about a 10 % conversion, followed by the production of the corresponding hydroxide and ketone. On using the transition metal salt type, these three components were formed at the start of the reaction ; the hydroperoxide formation ratio was comparatively smaller and production of oligomer, larger. With radical forming catalysts, hydrogen abstraction led to the smooth formation of peroxy radicals and production of hydroperoxide. Hydroperoxide gradually decomposed with the transition metal salt type, excess amount of alkoxy and peroxy radicals were produced at the start of the reaction.
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  • Minoru AOYAMA, Hiromu KANEMATSU, Masato TSUKAMOTO, Shigeru TOKAIRIN, I ...
    1993 Volume 42 Issue 9 Pages 680-684
    Published: September 20, 1993
    Released: October 16, 2009
    JOURNALS FREE ACCESS
    Assessment was made of the stabilization of fish oil, rich in highly unsaturated fatty acids, by several antioxidants at 5, 20, and 60°C. Antioxidants used were a mixed tocopherols concentrate (m-Toc), L-ascorbyl palmitate (Ap), dibutylhydroxytoluene (BHT), propyl gallate (PG), t-butylhydroquinone (TBHQ) and m-Toc combined with one or two of the others. Their added amounts were 0.1 and 0.2 % for m-Toc and 100 ppm for the others. In storage at 5°C, TBHQ markedly suppressed rapid increase in peroxide and carbonyl in fish oil. Antioxidant activity decreased in the order of TBHQ>PG>BHT>AP>m-Toc. m-Toc in combination with other antioxidants enhanced antioxidant activity. The most effective combination was that with TBHQ, followed by AP and PG. In storage at 20°C, the order of antioxidant activity was the same as at 5°C. Antioxidant effectiveness decreased with increase in storage temperature. Owing to the rapid rate of oxidation, no significant antioxidant activity could be seen at 60°C.
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  • Yasuo GAMA, Yoshihiro KAWAGUCHI
    1993 Volume 42 Issue 9 Pages 685-686
    Published: September 20, 1993
    Released: October 16, 2009
    JOURNALS FREE ACCESS
    The esterification of five kinds of methyl D-glycosides with S- (2-pyridyl) decanethioate in pyridine for 8 h at 90°C regioselectively proceeded to give methyl 6-O-decanoyl-D-glycosides in good yield.
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