Zeeman patterns of the nuclear Quadrupole resonance line of I
127 were studied with a single crystal of iodine at medium and weak magnetic fields. The asymmetry parameter of coupling, η, and the angle between bond axis of the iodine molecule and crystallographic
c axis, \varphi, were determined from the pattern at a medium magnetic field of about 120 gauss. The result was η=−0.16±0.01 at 14°C when crystallographic
b axis was chosen as
x axis and \varphi=31°38′±60′. The absolute value of η is in accord with the value obtained by the two resonance frequencies, i.e. 0.151±0.001 at 11°C, \varphi agrees with that obtained by the X-ray diffraction, 32°4′. At a weak magnetic field, Zeeman patterns of the fine structure of iodine were examined at three directions of magnetic field against the iodine crystal, i. e. the
b axis, the
c axis and the direction of 60° from the
b axis in the
bc plane. Behaviour of the superregenerative detector used for these N.Q.R. measurements was studied and the observed shape of the resonance line is discussed.
抄録全体を表示