In order to clarify the influence of shotcrete in the underground facility on the groundwater chemistry, an in-situ closed test of the mock-up tunnel was conducted at the depth of 500 m in granite. Portlandite, ettringite, gibbsite, K
2CO
3, natron, amorphous silica, calcite and brucite / nesquehonite were identified as the dominant minerals affecting the water chemistry. Furthermore, the shotcrete constructed in the tunnel has a reaction capacity which can produce about 570 m
3 of alkaline groundwater (pH 12.4) saturated with Ca(OH)
2. The estimation would improve the accuracy of prediction analysis of the long-term chemical influence of cement materials after the tunnel closure.
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