The highly toxic tributyltin (TBT) compounds used as biocides in ship antifouling paints have been released to aquatic environments. Because TBT has low solubility and high hydrophobicity, it is easy to be accumulated in the harbor sediments.
In this study, we investigated the distribution characteristics of TBT, dibutyltin (DBT) and monobutyltin (MBT) in sediments and in sea water column at Nagoya port. As a result, the concentration of TBT in seawater was found to be lower than those of DBT and MBT. However, TBT in sediments was still high concentration. The release flux of TBT from sediments to the water column was calculated to be about 2 to 13 g-Sn/day in all over the port. Good correlation between distribution coefficient
Kd (=
q/Cp) and amount of the organic matter in the sediment particle (TOC) was found. We suggested that Kd was affected by organic carbon mineralization processes. Finally, we estimated the behavior of three tin compounds at the entrance and the inner part of the harbor, and demonstrated that TBT in sediments was the main pollution source in the marine ecosystems.
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