Calcium phosphates have been used safely and effectively as bioceramics for the past three decades in dental and medical practice. Of calcium phosphate bioceramics, hydroxyapatite (HA), β-tricalcium phosphate (β-TCP), and a mixture of these calcium phosphates (BCP) are extensively used as bone substitutes. When placed in bony defects, they do not inhibit, but rather promote new bone formation. The ability to cause new bone formation is defined as "osteoconduction", and bioceramics that show osteoconduction are employed as bone substitutes and scaffolds in bone tissue engineering. In this review, material properties of orthocalcium phosphates, including HA and carbonate-containing apatite (CA), are discussed, together with their preparation methods and sintering behaviors. Some emphasis has been placed on the reviewer's work.
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