In electrolytic experiments introduced in general chemistry textbooks for high schools, colleges, and universities in Japan, only limited examples appear to observe electro-generated products, for example H
2 and O
2 evolution during the water electrolysis and metal deposition during electroreduction of corresponding metal ions. In order to make an impact upon the students, to attract the interest of them, and to enhance their understanding about electrolysis, the visualization of the metal ions electro-generated from the metal anodes was tried using their coloration reactions. Iron, copper, and lead rods were employed as the metal electrodes because of the easy availability and low prices. During the electro-oxidation, generated Fe
2+, Cu
2+, and Pb
2+ could be visualized as Turnbull Blue, bluish white Cu (OH)
2 and dark blue [Cu (NH
3)
62+], and the precipitation of white PbCl
2 when they reacted with [Fe (CN)
63-], aqueous ammonia, and Cl
-, respectively. On the other hand, OH
- generated on the cathode could also be visualized by phenolphthalein. These coloration and precipitation reactions were observable radially from the metal rod electrodes and the reaction rates depended on the electrolytic current. The visualization was experimentally performed at an actual chemistry class and the utility value was estimated. As a result, all the students could observe the visualization and both the questionnaires and reports submitted by them included their affirmative impression about the understanding about the electrolysis.
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