Journal of the Society of Materials Engineering for Resources of Japan
Online ISSN : 1884-6610
Print ISSN : 0919-9853
ISSN-L : 0919-9853
Volume 7, Issue 1
Displaying 1-11 of 11 articles from this issue
  • Kenzo KON, Akinori SATO, Shigeo TSUJIKAWA, Yoshihiro HISAMATSU
    1994 Volume 7 Issue 1 Pages 5-12
    Published: September 30, 1994
    Released on J-STAGE: October 28, 2010
    JOURNAL FREE ACCESS
    The crystallographic orientation of fractured surface in both intergranular and transgranular stress corrosion crackings was examined by changing the angle (θ) between specimen axis and grain boundary on SUS304 coarse columnar crystals with ‹100› growth direction. Intergranular cracking occurs at θ=60° and 90°, transgranular cracking at θ=0°, and both mixed crackings at θ=30° and 45°. Even on specimens fractured at grain boundary, many cracks were also observed in grains. Grain boundaries whose planes are closer to {100} and/or {110} of adjacent crystals have higher susceptibility to cracking. This seems to be closely related to the fact that the susceptibility to transgranular stress corrosion cracking is higher on {100} and {110}.
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  • Yoshio TAKAHASHI, Yoshihiro SASAKI, Jun ITO, Qi TIAN, Akimasa HORI
    1994 Volume 7 Issue 1 Pages 13-20
    Published: September 30, 1994
    Released on J-STAGE: October 28, 2010
    JOURNAL FREE ACCESS
    In the oil hydraulic system, the internal oil flow in the controlled elements should be analyzed by considering the flow pattern in order to improve the controllability of the system.
    In previous paper, the boundary element method was applied to these problems, and the velocity profiles in the hydraulic controlled valve were examined.
    In this paper, the velocity profiles in the spool valves of the various shapes were simulated by the boundary element method, and by using the obtained velocity vectors, these steady flow axial forces were calculated and compared. The most suitable shape of the spool valve, which can be improved the controllability of the hydraulic controlled valve of a spool type, was presented.
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  • Yukie NAKANO, Akira SATOH, Atsushi HITOMI, Takeshi NOMURA
    1994 Volume 7 Issue 1 Pages 21-27
    Published: September 30, 1994
    Released on J-STAGE: October 28, 2010
    JOURNAL FREE ACCESS
    Effect of microstructure on load life characteristics of insulation resistance (IR) has been studied with multilayer ceramic capacitors with Ni-electrode. It is found that the formation of oxygen vacancies under the firing in reducing atmosphere and the discrepancy of grain boundary composition from the nominal composition are the causes of the short life time. In case of high oxygen partial pressure at annealing, the formation of oxygen vacancies was suppressed and the IR load life time was prolonged. Donor additives such as Y2O3 are also valid to suppress the formation of oxygen vacancies.
    The suppression of the formation of oxygen vacancies and the control of grain boundary chemistry were effective to prolong the IR load life time.
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  • Shoji GOTO, Tetsuya TSURUGA, Setsuo ASO, Michihiro TAGAMI, Akira MUTO
    1994 Volume 7 Issue 1 Pages 28-35
    Published: September 30, 1994
    Released on J-STAGE: October 28, 2010
    JOURNAL FREE ACCESS
    In order to investigate a fabrication process for high strength aluminum=ceramic composites (Al-Al2O3, Al-Si3N4, Al-SiC), the composites were made by inserting the ceramic rods into molten aluminum at 1173K for various times up to 7.3ks. The relation between the structure and shear strength of the aluminum-ceramics interface in the composites was investigated. The shear strength was determined from resistance for shear deformation at the aluminum-ceramics interface. It was found that except for Al-Al2O3, the reaction layers of Al4C3 and AIN are formed at the interface regions of Al-SiC and Al-Si3N4, respectively and that the strength depends on the thickness and morphology of the rection layers. The optimum strength is obtained by heating at 1173K for 0.9-1.2ks, which is about 3-4 times that estimated for shear strength of alumimum matrix. The strength is higher in order of Al-Al2O3, Al-Si3N4 and Al-SiC.
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  • Shigekazu SUMTA
    1994 Volume 7 Issue 1 Pages 36-41
    Published: September 30, 1994
    Released on J-STAGE: October 28, 2010
    JOURNAL FREE ACCESS
    Thin films of three layers (p-type/i-type/n-type) amorphous silicon (a-Si:H) and boron phosphide (BP) were investigated by means of Fourier transform infra-red (FTIR) spectroscopy and electron spin resonance (ESR). The formation ratio of (B-H)/(P-H) bonds in BP film, as functions of SiH, and PH3 gas flows, was evaluated by magnitude of stretching vibration. As for a-Si, higher order bond of-(Si-H2)-n, which may deteriorate the efficiency of solar energy conversion (ESEC), was distinguishable from Si-H single bond. The number of unpaired electron spins formed in 5 % ESEC a-Si:H, 7.99-1013 (spin/gram), was 73% larger than that in 8% ESEC a-Si:H.
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  • Kenji KOSEKI, Atsushi HITOMI, Kenji HORINO, Junko YAMAMATSU, Takeshi N ...
    1994 Volume 7 Issue 1 Pages 42-49
    Published: September 30, 1994
    Released on J-STAGE: October 28, 2010
    JOURNAL FREE ACCESS
    Effect of process parameters as mixing and firing conditions on the varistor characteristics of BaTiO3-SrTiO3-CaTiO3 system ceramics has been studied with special attention to the micro-and nano-structures. It is shown that well mix ing and control of Po2 of ambient atmosphere during firing are most effective to attain high α (coefficient of V-I nonlinearity). In case of high Po2, anomalous grain growth is predominant. On the other hand, in case of low Po2, uniformly sized grain structure can be observed, but grain growth is insufficient. Adequate grain size and uniform microstructure are required for achieving high α. HRTEM observation showed grain boundary layer for high a ceramics, and facet grain boundary for low α ceramics.
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  • Masaharu HONDA, Yasuo KOBAYASHI
    1994 Volume 7 Issue 1 Pages 50-57
    Published: September 30, 1994
    Released on J-STAGE: October 28, 2010
    JOURNAL FREE ACCESS
    The resistance of commercial austenitic stainless steel, SUS 304 L, to stress corrosion cracking in a 5% NaOH-2% Na2S-2% Na2CO3-0.2% Na2SO4-0.1% NaCl-H2O solution at elevated temperatures has been studied by immersion tests and electrochemical measurements.
    A mixture of intergranular corrosion cracking and transgranular cracking was observed at the fractured U-bend specimen immersed in the test solution at 423K. The effects of solution composition and test temperature on the occurrence of stress corrosion cracking were examined. It was found that both the presence of Na2S in the solution and the temperature higher than 423 K was necessary to occur stress corrosion cracking and the presence of sodium chloride, sodium carbonate, and sodium sulfate had little effect on stress corrosion cracking occurrence. Cracking of U-bend stressed specimens was found to occur at a potential near the active/passive transition range of SUS 304 L. The results are discussed with reference to electrochemical behavior and the analyses of surface corrosion films.
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  • Hiroshi YAMADA, Yutaka OISHI, Ryu WAKAMATSU, Tamiya FUJIWARA
    1994 Volume 7 Issue 1 Pages 58-66
    Published: September 30, 1994
    Released on J-STAGE: October 28, 2010
    JOURNAL FREE ACCESS
    The electrical breakdown phenomena in mixtures of n-hexane and acetophenone have been studied using an image converter camera in conjunction with a photo optical current measuring system. It was shown that aspects of streamer development for both polarities in n-hexane are remarkably changed by a small amount additive of acetophenone. With higher additive rate of acetophenone, the negative streamer is changed to be more filamentary than that in plain n-hexane and to resemble the positive streamer in cyclohexane. The results are consistent with models of a breakdown mechanism based on a field ionization process for positive polarity and Auger-like electron emission process for negative polarity.
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  • Noboru TAGUCHI, Takao OTOMO, Kazuo KOIKE, I CHYO, Minehiro MIZUNO
    1994 Volume 7 Issue 1 Pages 67-75
    Published: September 30, 1994
    Released on J-STAGE: October 28, 2010
    JOURNAL FREE ACCESS
    The Values of emf of the galvanic cell (+) Mo |Mo (s), MoO2(s)| ZrO2(+MgO)| FexO (in slag), Fe |Ag| Fe (-) involving zirconia solid elektrolyte have been measured at 1467K-1641K in order to obtain the activity of FexO in FexO-B2O3 system molten slag and the standard free energy of formation of FexO.
    Activity of B2O3 were also determined by virtue of Gibbs-Duhem integration (α-function integration).
    The standard free energy of formation of FexO. was determined as the following equation:
    ΔG° (FexO) /kJ·mol-1=-264.3+0.06486T
    Activity of FexO deviates from negative to positive on the NFexO=0.55 at 1473 K and NFexO=0.64 at 1573K from Raoult's law, and show constant value, 0.20, independent of temperature over the two liquids phase range below NFexO=0.48. Activity of B2O3 show constant value, 0.65, over the same two liquids phase range and decrease beyond NFexO concentration, 0.48.
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  • Kaneko TAKAHASHI, Etsuro YAMADA, Ai FUJIEDA
    1994 Volume 7 Issue 1 Pages 76-84
    Published: September 30, 1994
    Released on J-STAGE: October 28, 2010
    JOURNAL FREE ACCESS
    Measurements have been made by the steady state comparison method for the effective thermal conductivity of the clothing materials which consist of fiber (discontinuous phase) and air (continuous phase or matrix). The influence of the factors affecting the effective thermal conductivity of clothing materials is discussed. The experimental apparatus and the test specimen are inserted into a box which is able to control the humidity or the pressure inside it.
    The thermal conductivity increases slightly with temperature for any specific density of clothing materials in the present experimental range in a similar way to that of the air, and it is also increases with the volume fraction of fibre except small fraction range. The effective thermal conductivity is, however, almost independent to relative humidity for cotton cloth and polyester one.
    Experimental result are compared to predicting equations for the fibrous materials, and the one which has wider range applicability has not been found from among the existing equations.
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  • Tomoyoshi SHOJI, Masaki HOSOKAWA, Kazutaka MAKINO
    1994 Volume 7 Issue 1 Pages 85-93
    Published: September 30, 1994
    Released on J-STAGE: October 28, 2010
    JOURNAL FREE ACCESS
    The powder materials are used in various field of industry as raw or intermediate materials. And many kinds of powder unit operation handle these powder materials, but various phenomena of powder have not yet been elucidated sufficiently. Fundamental relationship between powder surface properties and behavior is expected to be discussed as one of important subjects.
    In this paper, calcium carbonate is used as test packing powder and powder packing operation is fundamentally discussed. And the effects of powder surface improvement on initial bulk density distribution are experimentally and thermophsically discussed using X-ray radiograph system. As a results of it, the optimum conditions to generate the most homogeneity of powder density distribution is pointed out to exist.
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