The Values of emf of the galvanic cell (+) Mo |Mo (s), MoO
2(s)| ZrO
2(+MgO)| Fe
xO (in slag), Fe |Ag| Fe (-) involving zirconia solid elektrolyte have been measured at 1467K-1641K in order to obtain the activity of Fe
xO in Fe
xO-B
2O
3 system molten slag and the standard free energy of formation of Fe
xO.
Activity of B
2O
3 were also determined by virtue of Gibbs-Duhem integration (α-function integration).
The standard free energy of formation of Fe
xO. was determined as the following equation:
Δ
G° (
FexO) /kJ·mol
-1=-264.3+0.06486
TActivity of Fe
xO deviates from negative to positive on the N
FexO=0.55 at 1473 K and N
FexO=0.64 at 1573K from Raoult's law, and show constant value, 0.20, independent of temperature over the two liquids phase range below N
FexO=0.48. Activity of B
2O
3 show constant value, 0.65, over the same two liquids phase range and decrease beyond N
FexO concentration, 0.48.
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