A fullerene plasma consisting of positive potassium ions, huge negative C
60 ions, and residual electrons is generated in a Q machine, which has traditionally been used for plasma physics studies, under the influence of the mass production of fullerenes by an arc discharge method. The fullerene plasma shows novel behaviors associated with collective phenomena such as wave, instability, cross-field transport, and structure formation, Drastic changes in thin-film structure and the quality of K-C
60 compounds are observed, and endohedral metallofullerene K@C
60 is effectively formed in accordance with the bias control of the fluxes and energies of K
+ and C
60- flowing into a substrate immersed in this plasma.
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