表面科学
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
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29 巻, 7 号
選択された号の論文の11件中1～11を表示しています
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巻頭言
第27回表面科学講演大会論文特集 [I]
論文
  • プロトン導電性酸化物エピタキシャル薄膜の作製とその構造および導電特性評価
    井口 史匡, 鶴井 隆雄, 佐多 教子, 湯上 浩雄
    原稿種別: 論文
    2008 年 29 巻 7 号 p. 396-400
    発行日: 2008/07/10
    公開日: 2008/07/18
    DOIhttps://doi.org/10.1380/jsssj.29.396
    ジャーナル フリー
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    Epitaxial thin films of 5 mol% Y-doped BaZrO3 (BZY5) proton conducting oxide were fabricated on MgO and Nb-doped SrTiO3 single crystal substrates using PLD method. Crystal structure, microstructure and electrical properties in in-plane and perpendicular directions of those films were studied. BZY5 is grown epitaxially over 700oC, and its epitaxial relationship is typical “Cube on Cube type”. TEM and AFM observations reveal that the films consist of columnar structure. Electrical properties in in-plain direction show significant lower conductivity and higher activation energy than that in perpendicular direction, and the properties are close to that of grain boundary in ceramics, while the electrical properties in perpendicular direction are similar to that of bulk in ceramics. These results suggest that the interfaces between columnar crystals even in epitaxial thin films prevent proton migration as the grain boundaries in ceramics do.
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  • Si(110)-16×2単一ドメイン表面の作製
    山田 洋一, Antoine GIRARD, 朝岡 秀人, 山本 博之, 社本 真一
    原稿種別: 論文
    2008 年 29 巻 7 号 p. 401-406
    発行日: 2008/07/10
    公開日: 2008/07/18
    DOIhttps://doi.org/10.1380/jsssj.29.401
    ジャーナル フリー
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    Widely well-defined Si(110)-16×2 single-domain surface has been fabricated utilizing the electromigration of the surface atoms. Tuning the direction of the dc during resistive heating to that of the surface reconstruction row realizes an alignment of the rows in one direction producing a mm-wide single-domain of 16×2 structure. The fabricated single-domain shows number of useful characteristics such as a strong one-dimensionality and the surface homochirality, suggesting various applications.
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  • 角度分解光電子分光による金属/酸化物界面の研究
    —Cu吸着ZnO極性表面の価電子バンド構造—
    小澤 健一, 大塲 由香子, 枝元 一之, 十河 真生
    原稿種別: 論文
    2008 年 29 巻 7 号 p. 407-412
    発行日: 2008/07/10
    公開日: 2008/07/18
    DOIhttps://doi.org/10.1380/jsssj.29.407
    ジャーナル フリー
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    Angle-resolved photoemission measurements are carried out to investigate the valence electronic structures of two different ZnO surfaces that are (0001) Zn-terminated (ZnO-Zn) and (000-1) O-terminated (ZnO-O) surfaces, and also of Cu clusters supported on these surfaces. On the clean ZnO surfaces, two valence bands are observed at ∼4 and 5−8 eV with a clear dispersion feature. Although these bands are associated with the bulk bands, it is found that the dispersion widths of the bands exhibit the termination dependence of the polar ZnO surfaces. Deposition of Cu on the polar ZnO surfaces induces downward bending of the ZnO band. Magnitude of Cu-induced bending is larger on ZnO-O than on ZnO-Zn. This indicates that the Cu—ZnO interface interaction is greater for the Cu/ZnO-O system than for the Cu/ZnO-Zn system. The analysis of the Cu 3d band structure implies that coupling between the Cu 3d band and the ZnO band is operative at the Cu—ZnO-O interface, whereas such coupling seems to be missing at the Cu—ZnO-Zn interface. We propose that the effect of electronic coupling is one of the factors that determine the interface interaction between the Cu cluster and polar ZnO surfaces.
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  • 超短パルスレーザー駆動X線管を用いた時間分解蛍光X線分光システムの開発
    山田 秀尚, 村上 洋, 島田 幸洋
    原稿種別: 論文
    2008 年 29 巻 7 号 p. 413-417
    発行日: 2008/07/10
    公開日: 2008/07/18
    DOIhttps://doi.org/10.1380/jsssj.29.413
    ジャーナル フリー
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    A femtosecond-laser-driven X-ray source and an X-ray focusing system have been developed for the time-resolved X-ray fluorescence spectroscopy. The X-ray source, in which a plasma cathode induced by a 1013-W/cm2 laser pulse serves as an electron source of an X-ray tube, provides 109 Cu Kα photons in 4πsr per pulse. The X-ray pulse duration is measured to be about two hundred nanoseconds. Emission analysis of the plasma cathode indicates that the temporal characteristics of the X-ray pulse are determined by the dynamics of the plasma particles under the electrostatic shielding against the applied voltage in the X-ray tube. As for the X-ray focusing system, a focal spot size by a polycapillary lens is measured and the enhancement of X-ray fluorescence intensity due to the lens is demonstrated.
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ノート
研究紹介
  • 異種分子が創る二次元分子混晶膜
    若山 裕, Anirban BANDYOPADHYAY, Esther BARRENA, Dimas G. de OTEYZA
    原稿種別: 研究紹介
    2008 年 29 巻 7 号 p. 421-426
    発行日: 2008/07/10
    公開日: 2008/07/18
    DOIhttps://doi.org/10.1380/jsssj.29.421
    ジャーナル フリー
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    Self-assemble monolayers of binary molecules were studied by scanning tunneling microscopy. Di-indenoperylene (DIP) and fluorinated copper-phthalocyanine (F16CuPc), which are p-type and n-type organic semiconductors respectively, were co-deposited in ultra-high vacuum on Au(111) and Cu(111) surface. STM observation exhibited the molecules formed well-ordered intermixed monolayer on the metal surfaces. Theoretical calculation revealed C-F…H bonding between neighboring F16CuPc and DIP was a dominant force for the ordered phase formation. Orientation, alignment and domain formation were determined by balancing molecule-substrate interaction as well as such intermolecular interaction, and as a consequence showed dependency on the metal substrates and ratios of the molecules. Thus, the ordered phases were formed only at certain molecular ratios and were named as “molecular alloys” after those of inorganic materials.
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ポピュラーサイエンス
  • 原子間力顕微鏡による毛髪の微細構造と物性の研究
    北野 宏樹
    原稿種別: ポピュラーサイエンス
    2008 年 29 巻 7 号 p. 427-431
    発行日: 2008/07/10
    公開日: 2008/07/18
    DOIhttps://doi.org/10.1380/jsssj.29.427
    ジャーナル フリー
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    The hair has a complicated hierarchical structure which is composed of hydrophobic and hydrophilic components. Study of the mechanical properties of each components is important in order to understand the structure of the hair microscopically and to develop hair care products. The objects of this study are to evaluate the mechanical properties and fine structures of human hair at the same point and under the natural environment by taking the advantages of Atomic Force Microscopy (AFM). The force-curve method using stiff cantilevers in order to deform a sample by AFM enable us to evaluate Young's modulus and a fine structure simultaneously at the same point. In this study, we applied this method also to the cross section of the hair in order to evaluate the degree of hair damage. In an application we found that the Young's modulus was improved when the damaged hair was treated by L-theanine solution and that especially Young's modulus of macrofibril was recovered. This method is thus very useful to appraise the effectiveness of hair care components.
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