Pulp with pitch and its three components-resin acid, high-class unsaturated fatty acid and unsaponifiable materials-attached to it was washed first with water once and next with a detergent twice to see the pitch-eliminating action of the detergent.
Result.
1) The detergents served the purpose well, except water, white water from the decker, salts of alkaline earth metals and the hydroxide solution of these ; a waste solution of diluted sulfuric acid, hot water and 1% caustic soda were among the most effective ; anionic and nonionic surface-active agent removed more than half the pitch content, but when used more than twice, either detergent failed to produce any further result.
2) The resin acid content was reduced 2.9% by water used in the first washing of the pulp and in a still smaller percentage by a detergent used in the second washing ; as may be supposed from its chemical nature, resin acid was most easily eliminable by a 1% alkaline solution, the total pitch content decreasing 34% on the second washing with this detergent and 43% on the third. This detergent was followed in the potency of this action by anionic and nonionic surface-active agent.
3) The unsaturated fatty acid contained was reduced 35% by water used in the first washing, 50% or more by a detergent used in the second. The third washing produced no better result and was practically unnecessary. A water solution (pH 4.2) of hydrochloric acid, when used In the second and third washing was less effective than water. The detergents answering this purpose were, beginning with the most effective ; anionic, nonionic surface-active agent, an alkaline solution, hot water and a dilute sulfite waste liquor.
4) The unsaponifiable material contained was reduced 5.6% by the water used in the first washing and 10% or less by a detergent used in the second or the third washing, where as it was reduced 20% or more when the pulp was washed with an anionic or nonionic surface-active agent.
5) Pitch and any of its component were much effectively eliminated by anionic and an nonionic surface-active agent than by any other detergent. An alkaline solution served the purpose better than any other form of unsaturated fatty acid, and a dilute sulfite waste liquor better than water and water kept at pH 4.2.
6) This experiment has shown that the first substance to be taken into acconnt in an attempt to minimize pitch trouble is unsaturated fatty acid and that the detergents to be used for removal of this substance are, beginning with the most effective : anionic and nonionic surface-active agent, and then alkaline solution, hot water, dilute sulfite waste liquor.
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