In order to obtain a better understanding of deresinating compounds in Akamatsu (
Pinus densiflora) pine wood extractives during kraft pulping, the effects of additives on the deresination of Sugi (
Cryptomeria japonica) and Sudajii (
Castanopsis cuspidata) wood chips during pulping and washing were investigated. The chemical additives used were as follows : methanol extractives of Akamatsu pine wood, four kind of surfactants (oleic acid, abietic acid, sodium laurylbenzenesulfonate, and polyoxyethylene (20) sorbitan monooleate) as reference compounds.
The solubilization of lipophilic dye (p-dimethyl-aminoazobenzene) by these chemical additives was also examined and the amount of dye solubilized was measured.
Concerning the deresinating compounds in pine wood extractives, the following results were obtained :
(1) There are some deresinating compounds in the methanol extractives of Akamatsu pine wood.
(2) The effectiveness of abietic acid for deresination during pulping was very low.
(3) The ethyl acetate-soluble materials of the methanol extractives of Akamatsu wood were separated into six fractions (fr.1-fr.6). Fraction 5 is neutrals and soluble in 4% NaOH aqueous solution at hexane/4% NaOH extraction. The deresination effectiveness of fr.5 was the highest in the additives studied here.
(4) In the dye solubilization examination, oleic acid was most effective at a solubilization temperature below 80°C.
(5) At 90°C, the amount of dye solubilized by Fraction 5 exceeded that of oleic acid.
(6) Some effective deresinating compounds may exist in Fraction 5 of the methanol extractives from Akamatsu pine wood.
抄録全体を表示