Our experiments were to find out the means of making a highly uniform pulp in chain-length distribution . At first, measurements were repeated on different kinds of pulps with regard to chain-length distribution.The results obtained were as follows :
(i) There are four parts in the differential distribution curve of the usual rayon pulp. (PD. about 900). These parts exist severally at about 1000-1300, 400-600, 200-300 and 0-100 of PD. and they all show relatively sharp peaks.
(ii) Pulp of low viscosity, (high alpha-cell. and PD. about 750) has to parts, severally at about 200-300 and 500-1000. The former curve rises in sharp peak, but the latter in flat one.
(iii) Pulp of high viscosity has three parts, at about 200-300, 1000 and 1300-1800 each, of which the last occupies the main part and shows a flat curve, while the other two are in sharp curves.
(iv) When the short fibers are removed from the usual rayon pulp, the distribution curve obtained is in a very sharp peak at about 1000.
Our conclusions from the above results are as follows :
(i) There are some periodic weak points in solid-cellulose for chemical operation, such as sulphite pulping procedure and it is understood that PD. 1000, 500 and 300 are easily made by chemical depolymerization.
(ii) We can not obtain a highly uniform pulp of chain-length distribution by chemical procedure alone ; mechanical screening at the last stage before drying has also to be used.
Our researches will be continued in order to throw more lights on the problems herein discussed.
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