Unbleached sulfite pulp, preliminary treated with chlorine water, extracted with Na
2SO
3 solution and washed with water, was subjected to cold alkaline purification at the consistency of 10%, with 3-12% solutions of NaOH, at the temperature of 25°C., for 1 hr. respectively.
A definite portion of every waste liquor was sampled, completed to an aliquot volume with water, and then (I) directly analysed by conductometric titration with N-HCl solution for the content of total alkali, (II) treated with ion-exchange resin (Amberite IR-120) to remove a greater part of free alkali, whose existence resulted poor end point in conductometric titration for the small amount of combined alkali, and then titrated potentiometrically and conductometrically with N-HCl solution for the accurate determination of combined alkali.
The amount of combined alkali is 1, 0-2, 5% (as equivalent NaOH) based on the weight of original pulp while that of total alkali is 28, 6-111, 0% on the same base.
Free alkali and absorbed alkali (apparent) were also estimated as follows,
Free alkali=Total alkali-Combined alkali
Absorbed alkali (apparent) =Originally used alkali-Total alkali.
Titration curves of II showed the presence of two kinds of acidic organic substance, i. e., A
1and A
2,
where NaA
1+NaA
2= NaA (total combined alkali).
The amounts of A
1 and A
2 in every waste liquor were estimated and their dissociation constants, KA
1 and KA
2, were calculated from pH values of corresponding equivalence points.
KA
1 and KA
2 are always in the order of 10
-4 and 10
-10 respectively.
From their dissociation constant data A-
1 and A-
2 were assumed to be RCOO
-+HCO-
3 and 1/2 CO-
3 respectively and then carboxyl content (sum of the low and high melecular parts) of every waste liquor was computed.
The amount of carboxyl group is 0, 24-0, 37% (as equivalent NaOH) based on the weight of original pulp and that of high molecular part is 1/3-1/5 of the total one.
The ratios of A/Na and A/Nao were also estimated, where A, Na, and Nao were the weight of organic substance dissolved in waste liquor, that of alkali combined with it, and that of alkali combined with carboxyl group respectively.
A/Na and A/Nao are 6-20 and 23-74, they are much higher than that (constant value of 4, 5) obtained in the case of hot alkaline purification previously reported.
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