This article discusses the propagating velocity of longitudinal pulse wave in polyethylene film varying according to stretching directions.
Assume a tape cut along the machine direction to be an
x-cut and a tape cut along the transferse direction a
y-cut. Then the following results are obtainable:
(1) The propagating velocity of longitudinal pulse wave of an
x-cut tape is low whether the tape is nonstretched,
x-stretched, or
y-stretched.
(2) The propagating velocity of longitudinal pulse wave of a
y-cut tape is low, whether the tape is not stretched or
x-stretched, but it is high, about 3000(m/sec), when
y-stretched.
(3) The orientation of the crystalline regions inspected by
X-ray diffraction shows that the
c-axis of the crystalline regions has a normal distribution with four peaks slightly inclined to the normal of the film and that the a axis has a normal distribution with two peaks in two directions slightly deviating from the width direction.
(4) The potential energy of Van der Waals is φ(R)=1/2∑<Ω>(-8.703×10
-58/R
6 -6.540×10
-102/R
12)(R cm) where ∑<Ω> is the sum total of all the specimens.
(5) From the potential energy of Van der Waals, the velocity of longitudinal pulse wave
v, and the elastic coefficient
E are calculable as follows: In the
a direction,
va 3420(m/sec) and
Ea 1.176 10
11(dyn/cm
2). In the
b direction,
vb 6280 (m/sec) and
Eb 3.995 10
11(dyn/cm
2). Assuming the distance between the neighboring chains in amorphous regions to be 5.00-5.20A,
vam is 760-1460(m/sec),
Eam is 0.68-3.4 10
10(dyn/cm
2) and the density is 0.794 0.888(g/cm
3).
(6) The average distance
R between the neighboring chains, is calculated from the strength distribution of
X ray diffraction.
R-5.20A.
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