Stability constants were determined for
60Co (II)-amino acid complexes in sodium perchlorate media at an ionic strength μ=0.67, using cation exchange resins. Stability constants were, for Co (II)-phenylalanine, log β1=4.4, log β2=8.2, log β3=11.7, for Co (II)-histidine, log β1=7.4. for Co (II)-valine, logβ1=4.3, log β2=8.5, for Co (II)-proline, log β1=4.1, and for Co (II)-tyrosine, logβ1=7.2, respectively. The abundance of Co (II)-amino acid complexes in seawater was calculated from these stability constants on the basis of chemical equilibrium, assuming the concentration of individual amino acid to be 10
-7 to 10
-9 mol
-1. It was inferred that the Co (II)-amino acid complexes are probably not formed abundantly in seawater while inorganic species of
60Co (II) may still be dominant for a short period of time after discharge into seawater as liquid waste.
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