KAGAKU KOGAKU RONBUNSHU
Online ISSN : 1349-9203
Print ISSN : 0386-216X
ISSN-L : 0386-216X
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Displaying 1-4 of 4 articles from this issue
Editorial Board
Physical Properties and Physical Chemistry
  • Naishu Yang, Hiroyuki Matsuda, Masaki Ota, Takaaki Tomai
    Article type: Research Paper
    2025 Volume 51 Issue 2 Pages 25-31
    Published: March 20, 2025
    Released on J-STAGE: March 20, 2025
    JOURNAL RESTRICTED ACCESS

    When nanoparticles have a particle size less than 10 nm, they begin to exhibit behavior similar to that of relatively large molecules or oligomers in solution, transitioning from “dispersion into the solvent” to “dissolution into the solvent.” As a result, it becomes necessary to understand their properties in terms of molecular-like, rather than particle-like behavior. In this study, the authors treated decanoic acid-modified ceria nanoparticles as pseudo-molecules and measured their solubility in various organic solvents with cloud point method using laser scattering technique. In the correlation of experimental data activity coefficient equations were applied which have been widely used in the petrochemical industry for distillation, liquid-liquid extraction, crystallization, etc. It was found that the solubility of decanoic acid-modified ceria nanoparticles depends on temperature, particle size, and solvent type.

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Transport Phenomena and Fluid Engineering
  • Haruki Furukawa, Mana Kosaka, Yoshihito Kato, Hyun-Gi Koh
    Article type: Note
    2025 Volume 51 Issue 2 Pages 32-34
    Published: March 20, 2025
    Released on J-STAGE: March 20, 2025
    JOURNAL RESTRICTED ACCESS

    Although there are many reports on the mixing power consumption, there are very few reports that quantitatively discuss the effect of impeller surface roughness on the power consumption. In the previous paper, the effect of surface roughness on the power consumption was experimentally verified by applying a process that simulated rust and material changes to the surface of impeller blades, and it was shown that the power consumption was not affected when the ratio of the height of the impeller surface roughness element to the impeller diameter was ε/d<0.0125. In this paper, the roughness of impeller edge was further investigated. It was found that the roughness of impeller edge slightly increased the power consumption.

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Materials Engineering and Interfacial Phenomena
  • Kana Kimoto, Sou Nagasoe, Takashi Katayama, Saki Kobaru, Masahiro Yosh ...
    Article type: Research Paper
    2025 Volume 51 Issue 2 Pages 35-41
    Published: March 20, 2025
    Released on J-STAGE: March 20, 2025
    JOURNAL RESTRICTED ACCESS

    It is important to develop new artificial feed for bivalves to prepare for future food crises. In this study, we examined the potential of hydrogel microcapsules with glucose residues on their surface as the new feed by investigating whether the capsules were specifically taken up by bivalves through recognition of the glucose residue by bivalve. Starch with glucose residues and gelatin without glucose residues were used as capsule materials. It has been reported that particle size was also an important factor to achieve intake of the particles by bivalve. We prepared starch and gelatin hydrogel microcapsules that had suitable diameter (5–20 µm) for intake by juvenile bivalve mollusks. Feeding experiments using these microcapsules quantitatively showed that starch hydrogel microcapsules were more efficiently taken up by the bivalve gills than gelatin hydrogel microcapsules. Furthermore, we were able to visually confirmed that the starch hydrogel microcapsules were significantly more abundant in the stomach than gelatin microcapsules by the observation of stomach tissue sections. These results suggest the high potential of starch hydrogel microcapsules with glucose residues on their surface as new artificial feed for bivalve.

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