Chemical engineering
Print ISSN : 0375-9253
Volume 20, Issue 9
Displaying 1-7 of 7 articles from this issue
  • Yasuo Yamasaki
    1956 Volume 20 Issue 9 Pages 474-480
    Published: September 01, 1956
    Released on J-STAGE: May 26, 2009
    JOURNAL FREE ACCESS
    The calculated mean emissivity of cylindrical gas masses is presented in this paper which is applicable practically to all shapes of cylinders. The radiant heat exchange between the gas mass and the cylinder wall can be computed by making use of the mean emissivity alone if the entire furnace wall is the heat-absorbing surface. However, if the furnace wall is made up of refractory surfaces and heat-absorbing surfaces, then the gas transmissivity between the component surfaces must be evaluated in order to find the radiant heat exchange. The gas transmissivity can readily be deduced from the absorptivity of the gas body contained between the two surfaces under consideration. In this paper is also presented the average absorptivity of the gas masses for the radiation between any two of the following surfaces, namely, the cylindrical surface and the two end surfaces.
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  • Yuzo Nakagawa, Satoshi Okuda, Masayoshi Oyabu
    1956 Volume 20 Issue 9 Pages 481-487
    Published: September 01, 1956
    Released on J-STAGE: May 26, 2009
    JOURNAL FREE ACCESS
    The object of the report is to explain the result of the investigation on a new rotational oscillating viscometer with coaxial two cylinders designed by the authors. Coefficient of viscosity η of liquid under test is obtainable from the logarithmic decrement λ of the damped oscillation of the inner hollow cylinder suspended by a steel wire of small diameter from the upper block, which is so contrived as to be kept in the fixed position by being pulled with a magnet during the test. The inner cylinder has no bottom plate but contains liquid in it, which also gives a resistance against rotation of this cylinder.
    As seen from the relation between λ and the dipped height of the inner cylinder in liquid, the end effect of this apparatus is negligibly small as compared with that of the ordinary viscometer of rotating cylinder type with a bottom plate.
    The relation λ vs. η is recognized to be straight in the region, η>1 poise, but it deviates from the straight line where the viscosity is as low as η<1 poise. Usually we can apply this viscometer to the measurement of viscosity in the wide range of η above 1 poise. Even when the viscosity is low, -η<1 poise-, it may be used keeping the sensibility of 0.1 centi-poise by setting a torsion wire of smaller diameter, although in this case it does not give the linear relation between λ and η as before.
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  • Yoshiro Mori, Naoshi Ototake
    1956 Volume 20 Issue 9 Pages 488-494
    Published: September 01, 1956
    Released on J-STAGE: May 26, 2009
    JOURNAL FREE ACCESS
    The presence of a set of rigid particles in a Newtonian liquid raises the viscosity of the liquid to a value ηs which is higher than the viscosity η0 of the liquid itself. The nondimensional ratio ηs0, which is known as the relative viscosity ηr of the suspension, might be a function of the fraction of the total volume of the suspension φv comprizing the particles.
    The most widely known expression for ηr, first obtained by Einstein, has the form of the equation 1. But this equation does not agree with the experimental results except for the case in which the concentration is very dilute. So many theoretical relationships, derived by Guth, Simha, Vand, Brinkman and others, for higher concentration, however, do not agree with the observed data in the range higher than 8-10 volume percentage, either. Now, Robinson considered that the specific viscosity in higher concentration was not only proportional to the volume fraction of solid, but to the reciprocal of free liquid volume fraction, and obtained the empirical equation in Table 1.
    Taking into account this consideration by Robinson and the observation by Bingham that the particles in the same stratum had the same velocity and did not change their mutual distances, the following theoretical relationship for the relative viscosity of general suspension system has been derived by the authors.
    (16)'
    where, d is the effective average diameter of particles, Sr is the volume specific surface, φv is the volume concentration and φvc is the limiting concentration at the full-packed state, where steady flow can occur without any deformation, fracture or grinding of particles.
    From this formula, the physical meanings of the two empirical constants k and S' in Robinson's equation can be explained as follows:
    in which, k is a function of particle shape, whose value becomes 3 for spherical particles, φvc, the limiting concentration, may be a function of particle shape and its size distribution.
    In a special case when the suspended particles are spherical and have equal size, the obtained formula becomes as follows, provided the value of φvc is assumed to be equal to 0.52, which is the volume fraction of solid in cubic packing of spheres of equal size.
    This formula agrees quite well with the observed values given by different writers over a wide range of concentration as shown in Figure 4. Figure 6 indicates the systematic variation of relative viscosity with changes in the relative fraction of large and small spheres in the suspensions. The plotted data are the experimental values by Eveson, Ward and Whitmore for the suspensions consisting of methyl methacrylate polymer spheres in an aqueous lead nitrate-plus-glycerol solution. The real lines are the theoretical results calculated by means of the equation (16)', using Furnas chart, Figure 5, for φvc. According to the equation 16, when 1/ηsp is plotted against 1/φv on condition that and 1/φv are constants, the graphs must be linear, and its intercepts are equal to 2/d·Sr and 1/φvc respectively. All the data reported were examined and they proved to agree approximately with this consideration as shown in Figs. 9-15. It is especially interesting to note that in Figure 14, the value of φvc is approximately equal to the concentration of the cake produced in the centrifuge.
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  • [in Japanese]
    1956 Volume 20 Issue 9 Pages 495-502
    Published: September 01, 1956
    Released on J-STAGE: May 26, 2009
    JOURNAL FREE ACCESS
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  • [in Japanese]
    1956 Volume 20 Issue 9 Pages 503-504
    Published: September 01, 1956
    Released on J-STAGE: May 26, 2009
    JOURNAL FREE ACCESS
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  • [in Japanese], [in Japanese]
    1956 Volume 20 Issue 9 Pages 505-506
    Published: September 01, 1956
    Released on J-STAGE: May 26, 2009
    JOURNAL FREE ACCESS
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  • [in Japanese]
    1956 Volume 20 Issue 9 Pages 507-512
    Published: September 01, 1956
    Released on J-STAGE: May 26, 2009
    JOURNAL FREE ACCESS
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