Thermal power plants are the biggest source of global warming because they emit huge amount of CO
2. CCS (Carbon dioxide Capture & Storage) system that separates CO
2 from boiler flue gas by using CO
2 capture solvent is expected for remarkable reduction of CO
2 emission from thermal power plants. This paper describes chemical absorption method of CCS for thermal power systems, especially the results of our research and development in refinement of amine solvent for CO
2 capture using ion exchange treatment. Sulfur oxides such as SO
4 and nitrogen oxides such as NO
3- are contained in boiler flue gas as impurities. These impurities block the adsorption of CO
2 and cause the significant performance degradation of CCS system. Adsorption and desorption behaviors of SO
42- and NO
3- by ion exchange resin are studied here in terms of small scale experiment and numerical analysis. The obtained results explain that two types of impurities such as SO
42- and NO
3- , in which SO
42- has larger adsorption energy onto ion exchange resin than NO
3- , show the temporal excess of NO
3 concentration in amine solvent after ion exchange treatment. It is concluded that knowledge acquired here can be extended for design of ion exchange resin tower for boiler flue gas of CCS plant operation.
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