Precipitation behaviour in Ni-8%Ti and Ni-10%Ti alloys at 550∼950°C has been studied by means of transmission electron microscopy and X-ray diffraction. The results are summarized as follows:
(1) Stable η-phase plates are formed directly from the supersaturated solid solution at high temperatures, while metastable α
2-phase cuboidal particles appear after aging for a short time at low temperatures. The latter process is observed at temperatures below 675°C for the Ni-8%Ti alloy and below 940°C for the Ni-10%Ti alloy.
(2) The distribution of α
2-phase particles is regular at temperatures below 575°C for the Ni-8%Ti alloy and below 900°C for the Ni-10%Ti alloy, while the distribution is at random at higher temperatures.
(3) The lattice parameter of α
2-phase decreases with rise in aging temperature.
(4) From the above results, the upper limits for the precipitation of α
2-phase and the formation of modulated structure are drawn on the Ni-rich side of the Ni–Ti diagram.
(5) X-ray side-bands are observed at the stage where a regular array of α
2-phase particles is formed.
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