The structure of quenched Ni
3(Mo, Ta) alloys containing 2 and 5 at% Ta was investigated by transmission electron microscopy. It was found that the DO
22-type ordered phase was formed in the Ni
3(Mo, Ta) alloy containing 5 at% Ta quenched from 1300°C. The changes in structure, interaction energy and strain energy with increasing Ta content are discussed. It is described by using a tetrahedron model that regions which take Ni
3Mo-type tetrahedron in
FCC lattice site will either extend or increase in number, or both with increasing Ta content. It has been deduced that the addition of Ta to Ni
3Mo alloy causes the V
2/V
1 to decrease, and by the addition of atoms having an atomic radius larger than that of Mo atoms, the tendency of the formation of the DO
22-type ordered phase increases.
View full abstract