Mineralogical Journal
Online ISSN : 1881-4174
Print ISSN : 0544-2540
ISSN-L : 0544-2540
Volume 14, Issue 1
Displaying 1-3 of 3 articles from this issue
 
  • A. S. SANDHU, Surinder SINGH, H. S. VIRK
    1988 Volume 14 Issue 1 Pages 1-11
    Published: 1988
    Released on J-STAGE: March 31, 2007
    JOURNAL FREE ACCESS
    The studies of each pit formation of fission fragment tracks in natural quartz are carried out using KOH, as the track etchant. The influence of crystallographic structure on the bulk etch rate, VG, the track etch rate VT, and the etching efficiency, η is reported. The value of fission track age is found to be the same for all the planes. It is observed that the annealing augments anisotropy of track revelation in the crystal. The activation energy, Ea, is found to vary with the crystallographic orientation.
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  • Osamu TAMADA, Kazuyoshi TANAKA
    1988 Volume 14 Issue 1 Pages 12-19
    Published: 1988
    Released on J-STAGE: March 31, 2007
    JOURNAL FREE ACCESS
    Semi-empirical molecular orbital study (CNDO/2) has been performed for a large cluster of atoms (Mg(1)3Mg(2)2Si2O22H26)0+ to evaluate cation charges of forsterite. Hydrogen (H) atoms were attached to outer oxygens of the cluster to keep local neutrality. The cluster included all the polyhedra which share edges with the Mg(1)O6 and Mg(2)O6 octahedra and the SiO4 tetrahedron under consideration for cation charges. The convergence in the energy minimization was successfully achieved for this cluster. The obtained cation charges were 0.62–0.63, 0.80–0.81 and 1.24–1.34e for Mg(1), Mg(2) and Si atoms, respectively. The charge of Mg(2) showed a larger value than that of Mg(1), which indicated that M(2) site of olivine was more ionic than M(1) site. This result is consistent with the previous works of experimental charge determination by X-ray method and calculation of electrostatic site potentials. The Si atom showed a higher valence value comparing with Mg atoms.
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