In order to adapt to the growing demands for smaller and more energy–efficient electrical equipment in recent years, the magnetic powder cores used in the passive elements that compose the circuit systems of such equipment must exhibit high magnetic saturation flux and low losses, while ensuring linearity in excitation response without magnetic saturation. Therefore, high saturation magnetization soft magnetic powder is suitable as magnetic powder core materials. Furthermore, in order to suppress inter–particle eddy current losses, forming an insulating shell on the particles is effective. Additionally, finer the particle size to minimize intra–particle eddy current losses would enable further loss minimization. Thus, high saturation magnetization soft magnetic nanoparticles with insulating shells are promising. In order to derive high saturation magnetization soft magnetic properties, body centered cubic (bcc) Fe–based alloys which is containing small amounts of solid solution elements for decline magnetic crystalline anisotropy are suitable. However, nanoparticle fabrication of Fe–based alloys involves the problem, including the risk of ignition, combustion, and explosion due to exposure or impact in air. Therefore, this study proposes Fe–based alloy nanoparticle clusters that can be safely handled in air. Focusing on crystal structure changes, hydrogen reduction via gas–solid reaction of Si or Al containing magnetite was employed as a synthesis method. The obtained particles were found to be clusters of Fe–based alloy crystallines, with cluster sizes in the micron range comparable to the size of magnetite. Magnetite containing small amounts of Al enabled smaller crystalline sizes while achieving higher saturation magnetization. Magnetite containing small amounts of Si allowed for higher saturation magnetization and low coercivity.
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