Synthesis of sodium magnesium phosphates by an oxidative decomposition method of EDTA-metal chelate with hydrogen peroxide were investigated. Three new compounds and trimagnesium phosphate pentahydrate (TMP5) were obtained. These compounds are NaMg
7 (PO
4)
5·12H
2O (described as NNa-1), NaMg
2 (PO
4) (HPO
4) ·3H
2O (described as NNa-2) and NaMg
4 (PO
4)
3·6H
2O (described as NNa-3), and these structures are orthorhombic, monoclinic and orthorhombic (or monoclinic), respectively.
These compounds are obtained by controlling the concentrations of Na
+, Mg
2+ and oxo-phosphate ions as mono phase of each compound. NNa-1 was successfully obtained by allowing to react the solution with the conditions of high pH,
R value (Mg
2+ /PO
43- molar ratio) =1.0 and lower concentration of sodium ion, NNa-2 was obtained under the condition of
R value = 0.1, and NNa-3 was obtained under the conditions of
R value=1.0 and higher concentration of sodium ion.
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