Journal of the Society of Inorganic Materials, Japan
Online ISSN : 2185-4378
ISSN-L : 1345-3769
Volume 11 , Issue 308
Showing 1-8 articles out of 8 articles from the selected issue
  • Kunihito KOUMOTO
    2004 Volume 11 Issue 308 Pages 3-13
    Published: January 01, 2004
    Released: March 07, 2011
    JOURNALS FREE ACCESS
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  • Kazuko FUJIWARA, Hideyuki YOSHIMATSU, Eiji FUJII, Koji KAWABATA
    2004 Volume 11 Issue 308 Pages 14-18
    Published: January 01, 2004
    Released: March 07, 2011
    JOURNALS FREE ACCESS
    CaCO3 powder was reacted with 2 mol% lactic acid and heated at 300°C to prepare the CaCO3 particles with porous surface layer. The specific surface area of the CaCO3 powder thus prepared was 1.8 times higher than that of the untreated powder. The hydrophilic property of the powder of particles with porous surface layer was improved due to its high surface area. The powder was homogeneously dispersed in water because of its hydrophilic property. Then the apparent viscosity of aqueous slurry of the CaCO3 powder decreased by a factor of 10, compared with that of untreated CaCO3 powder.
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  • Takeshi TOYAMA, Satoru ISHIKAWA, Tamotsu YASUE
    2004 Volume 11 Issue 308 Pages 19-25
    Published: January 01, 2004
    Released: March 07, 2011
    JOURNALS FREE ACCESS
    Amorphous calcium phosphate (Ca3 (PO4) 2·nH2O, ACP) with nanoparticles is known as a metastable precursor of various wet process calcium phosphate salts. It is necessary to take ACP from the liquid phase in a wet process as quickly as possible. However, under present technical conditions, synthesis of ACP is only possible by a wet process that presents difficulties for mass production. On the other hand, mechanochemical treatment is very effective for industrial mass production. Mechanochemical synthesis of ACP was tested by adjusting the mixtures of Ca (OH) 2 and NH4H2PO4 to Ca/P atomic ratios of 1.00-2.00, and ground for 0-2 h. X-ray intensity of the ground mixture was decreased by grinding at each Ca/P atomic ratio; and it was changed to ACP by grinding for 1 h. The result of TG-DTA analysis showed that the exothermic peak was observed, at an indicated ACP, at about 670°C. Also, the internal structure of the obtained ground substance was an amorphous layer to 35 nm depth from particle surface (75 vol%), Ca (OH) 2 and CaHPO4·2H2O (DCPD) mixture layer to 50 nm depth from particle center (15 vol%), and intercalation was DCPD layer of thickness 10 nm (10 vol%).
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  • Fumiaki MATSUSHITA, Naoyuki YAMAGUCHI, Kouichi IMASAWA, Tetsuji YAMANO ...
    2004 Volume 11 Issue 308 Pages 26-32
    Published: January 01, 2004
    Released: March 07, 2011
    JOURNALS FREE ACCESS
    Calcium sulfate is often used as a raw material for Autoclaved Aerated Concrete (AAC) to improve several properties. Microstructure and carbonation resistance of gypsum (CaSO4·2H2O) added AAC were investigated. Anhydrite (CaSO4) and hemihydrate (CaSO4·0.5H2O) recrystallized after autoclaving and filled the finer pores, while the total pore volume was unchanged. Fractal dimension obtained from the water vapor sorption isotherms data increased and Knudsen diffusion coefficient of carbon dioxide gas decreased with the increase of the gypsum content. Carbonation resistance was improved with increase in the gypsum content from 0 to 15 mass%. The mechanism of the increase of the carbonation resistance of the gypsum-added AAC is attributed to the decrease of the Knudsen diffusion coefficient associated with an increase in the fractal dimension of the liquid and gas interface.
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  • Akinori KOBAYASHI, Keizo MATSUDA, Kazumi FUJITA
    2004 Volume 11 Issue 308 Pages 33-42
    Published: January 01, 2004
    Released: March 07, 2011
    JOURNALS FREE ACCESS
    The synthesis of the potassium magnesium phosphates was studied by the oxidative decomposition method using EDTA-metal chelate. As a result, three potassium magnesium phosphates were successfully synthesized. These compounds are KMg7 (PO4) 5·12H2O (described as KM7P5H12), K9Mg10 (PO4) 9 (OH) 2·8H2O (K9M10P9H8) and KMg4 (PO4) 3·7H2O (KM4P3H7).
    These potassium magnesium phosphates were prepared under several conditions as follows : concentrations of K+ ion, Mg2+ ion, phosphate ion and H2O2, and initial pH. KM7P5H12 were prepared under the conditions of the Mg2+ /P (P : phosphoric oxyacid) molar ratio (described as R value) = 1.0 and low concentration of K+ ion and H2O2. K9M10P9H8 was prepared under the conditions of R value = 0.1 and the high pH reagion. KM4P3H7 was prepared under the conditions of R value = 0.2 and low concentration of H2O2.
    Three potassium magnesium phosphates did not change by aging them in KCl solution at 98°C, but KM7P5H12 and KM4P3H7 changed to K9M10P9H8 by aging them in K2HPO4 solution at 98°C. The relationship of phases equilibilium between three potassium magnesium phosphates was revealed.
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  • Hiroaki TAKEDA, Kiyoshi SHIMAMURA, Soichiro OKAMURA, Tadashi SHIOSAKI
    2004 Volume 11 Issue 308 Pages 43-49
    Published: January 01, 2004
    Released: March 07, 2011
    JOURNALS FREE ACCESS
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  • Toru OCHIAI
    2004 Volume 11 Issue 308 Pages 50-56
    Published: January 01, 2004
    Released: March 07, 2011
    JOURNALS FREE ACCESS
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  • Tetsuya MASUDA
    2004 Volume 11 Issue 308 Pages 57-62
    Published: January 01, 2004
    Released: March 07, 2011
    JOURNALS FREE ACCESS
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