Poly (
p-hydroxystyrene-3, 5-diazidobenzate) (PHS-DAB) which had two photoreactive sites, two azido group in one benzene ring, was newly synthesized in order to obtain photosensitive polymer developable by aqueous solution. Poly (
p-hydroxystyrene-
p-azidobenzate) (PHS-MAB) which had one azido group in one benzene ring, was also synthesized to compare the photosensitivity and solubility with it. Their photochemical behaviour was investigated and the following results were obtained. 1) PHS-DAB showed an absorption maximum at -250 and -320nm and it was certainly photoreacted even if the exposure light of 250W high pressure Hg lamp was filtered by the polyester film (-120μm). 2) In the case of low concentration (<10%) of photochemical group into the polymer, PHS-DAB showed paticularly photosensitivity higher than PHS-MAB in the rate of formation of insoluble part and in the gray scale method. 3) PHS-DAB was easily disolved in aqueous ethanol and aqueous NaOH solution and the degree of its insolubilization increased with increasing the content of photosensitive groups in the polymer.
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