Changes in spectral shapes of metallic surface composition obtained from stainless steel, stainless steel after heat-treatment at 900°C in atmosphere, stainless steel after hydrogen introduction and stainless steel after heat-treatment by boiling water were observed by soft X-ray appearance potential spectroscopy.
Stainless steel 304 surface seems to be covered by an oxidation layer of chromium and iron before sputtering and annealing. However, the surface layer observed after sputtering and annealing cycles consisted of pure chromium and iron. The peak ratio of Fe/Cr increases with sputtering and annealing.
Hardly any change in spectral shapes of stainless steel after heat-treatment at 900°C was observable by sputtering and annealing cycles.
Changes in spectral shapes of stainless steel after heat-treatment by boiling water were the same as stainless steel without treatment.
The Mn spectra of stainless steel were clearly observed only after hydrogen introduction, as compared with other forms of treatment.
抄録全体を表示