Liquid chemical wastes produced in the chemical experiment studies at Kanazawa Izumigaoka Senior High School, were the largest in quantity in Ishikawa Prefecture. The disposal of the wastes was costly, and to save the cost, our Chemical Research Club began to recycle silver and make silver nitrate from the wastes in 2000. The recycling was successful and the waste processing charge could be reduced significantly, and we presented details of the research at the Regional Symposium of Ishikawa High School Chemical Research Clubs. In 2002, we received solid chemical waste that contains mainly silver chloride and weighs about 2.7kg from the Chemical Research Club of Kanazawa Nisui Senior High School. The solid was dissolved in conc. liquid ammonia, and copper pellets were added in the solution. 273 grams of metallic silver could be recovered out of the solid waste 1.7 kg. Then, 30 grams of metallic silver was dissolved in conc. hydrogen nitrate and we obtained silver nitrate, 33g, which process proved the recycling of silver meets economical principle: The price of AgNO3 obtained is more than the cost of reagents used for the recycling.
We stepped forward to use the recycled silver by learning the textbook of early photography “Shashin-kyo Zusetsu (Camera and Photography, illustrated) ” by Shunsan YANAGAWA in 1867. Prof. Emeritus Eiji ITAGAKI at Kanazawa Univ. showed us the book and we rewrote the text in modern Japanese. Following the book, Collodion Photography was successfully reproduced with the camera designed and manufactured ourselves. With more than 30 trials, images of us were fixed on the Collodion plates.
Through the research, we studied that, by understanding the process step by step, the ancient complicated but established and once popular technology such as the Collodion Photography can be regenerated over the hundreds years.
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