Part I. The Specitic heat the Glasses Melted in Open Air.
1. 18 glasses in SiO
2•Na
2O-CaO system, 15 glasses in SiO
2-K
2O-CaO system, 18 glasses in SiO
2-Na
2O-K
2O system, 23 glasses in SiO
2-K
2O-PbO system, 34 glasses in B
2O
3-Na
2O-SiO
2 system and 11 SiO
2-Na
2O-CaO glasses containing MgO, ZnO, PbO, B
2O
3 or Al
2O
3, respectively, were melted in open air using platiunm or sintered alumina crucibles as the container.
2. The study has been extended to the extreme composition limits t which the tendency to crystallize makes impossible the preparation f glass even by laboratory methods.
3. By the method of mixture, the mean specific heat between bout 20° and 100°C was determined for these glasses.
4. By chemical analysis, it was confirmed for some glasses melted _??_ sintered alumina crucibles that the material dissolved out of the crucible was negligibly small.
5. The “molecular heat of glass” obtained from the batch composition and the specific heat of the glass was found to change linearly roportionally with the composition represented in mole percent. except or B
2O
3-Na
2O-SiO
2 system. Therefore, the molecular beat of a glass _??_ay be reposented as the sum of the apparent molecular heats of its _??_t oxides, which were determined as follows: CaO 10•3
5, SiO
2 _??_. PbO 11•4
5, Na
2O 16•2
5, K
2O 18•5
5. Namely, one and the same _??_stimeat oxide has always the same apparent molecular heat _??_ronghout all systems studied, except for B
2O
3-Na
2O-SiO
2 system.
6. It was also found that the values for CaO, SiO
2 and PbO were _??_ or nearly equal to the values of the separate oxides before combination. Assuming, from the picture of the atomic arrangement in lass, that this holds true for the oxides of the type RO or those confining more oxygen than RO, the apparent molecular heats of MgO, _??_O and Al
2O
3 were also determined from a few measurements as MgO _??_. ZnO 9•9_??_and Al
2O
3 20•2.
7. In B
2O
3-Na
2O-SiO
2 system, the iso-curves of the molecular _??_at of glass are not parallel straight lines as in the above eases, and _??_apparent molecular heats of the constituent oxides should be taken _??_ follows: SiO
2 11•0
5, Na
2O 16•2
5 (these values are the same as in the above cases), B
2O
3 15•0
5 when Na
2O≥20 mole percent, 15•3
0 when _??_
2O-10 mole percent and 15•5_??_ when Na
2O _??_0. The change of the _??_ for B
2O
3 with the Na
2O content is thought to be caused by the striation of the coordination number of B atom with the increase of a O content as much as about 18 mole percent.
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