With a high-vaeuum spectrograph of a modified Siegbahn type using a bent mica crystal focussing in the direction towards the spectral line and wave-lengths simultaneously, the non-diagram line of
Kα-series of F(9) were newly detected. And by use of semi-Moseley diagram their assignment has been done as they are homolog of
Kα', α
2, α
4 of higher element. And the form of the
Kα-lines of F and wave-lengths in many of its compounds such as LiF, NaF, KF, 2BeO-5BeF
2, CaF
2, BaF
2, AlF
3, K
2AlF
6 and F
2TaF
7. were determined microphotometrically, use being made of a step-sector dises and the half-width determined. Also the intensities relative to that of the FKα
1, 2 line were measured for the
Kα non-diagram line of various fluorine compounds.
The main result obtained are as follows:
(1) for all compounds in which the metal has the same valence, rather regular increase of wave-length of the F
Kα line with atomic number of the metallic atom was observed, (2) metallic atoms with different valencies has a tendency to shift towards shorter wave-length with valency; (3) the bandwidths of F
Kα
1, 2 line changes linearly with the reciprocal of the distance between closest neighbours; (4) the intensities of the F
Kα
3, 4 lines relative to that of F
Kα
1, 2 changes from compound to compound in pecnliars manner.
The latter phenomena was explained on the basis of the de-excitation of the initial state (1
s2p) of
Kα
3, 4 lines by an electron from the next atom by leakage through potential varrier between them and the quenching of the
Kα
3, 4 line occurs, which lead to conclusion that the anti-electron is conducted through the lattice and also as a measure of the degree of polarity
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