The distribution of manganese between precipipates of calcium carbonates, calcite and aragonite, and saturated aqueous solutions has been measured at 15, 25, 40 and 50°C. Calcite was precipitated from a calcium bicarbonate solution and aragonite was precipitated from a solution which contained magnesium perchlorate. Both systems obeyed the logarithmic distribution law, and distribution coefficients, λ were calculated by using the ratio of solubility product constants Karagonite/Krhodochrosite=291 at 25°C. Partition coefficient, λcai.=23.9, λarag.=0.102, excess free energy between ideal solid solution and real solid solution, Δ, μdcal.=5.40 kJ mol-1 and Δμarag.=19.7 kJ mol-1, were obtained. Differences of two excess free energy values is caused by the fact that rhodochrosite and calcite both belong to hexagonal system, but aragonite belongs to the rhombic one.
We investigated glucose and amino acid metabolism in tumors and other organs using whole body autoradiography with a short-lived positron emitter and a long-lived β emitter. The radioactive compounds used were 2-deoxy-2- [18F]-fluoro-D-glucose (18F-FDG) with a half life of 109.8 min and L- [methyl-14C]-methionine (14C-MET) with a half life of 5730 years. A Donryu rat weighing about 150 g was subcutaneously inoculated at the back with experimental tumors of AH 109A and AH 272.74 MBq (2 mCi) of18F-FDG and 740 kBq (20μCi) of14C-MET was administered and after 30 min, the rat was sacrificed. Whole body frozen sections were obtained using autocryotome. For the18F-FDG autoradiogram, the frozen sections were exposed to an X-ray film for 6 h. After seven days, these frozen sections were again exposed to14C-MET for a week. Cross-contamination was minimized by adjusting the exposure time, the interval of exposures and the administered dose. The accumulation of the tracers was represented as the optical density ratio of the tissue of interest to the muscle. The tumor ratios were 12.5 for18F-FDG and 8.6 for14C-MET showing the highest accumulation in the whole body autoradiogram. In contrast the inflammatory tissue ratios were 1.27 for18F-FDG and 0.77 for14C-MET showing very low amino acid metabolism. With the present double tracer whole body autoradiogram, 18F-FDG accumulation was seen in the brain and the heart but not to the liver as against14C-MET accumulation which was seen to the liver but not to the brain and the heart.
PTH levels were analysed in sera of the parients with receiving the maintenance hemodialysis, the vascular type of dementia and the orthopedics patients with bone-joints disorders, using PTH assay kits. There were the significant interrelationship among all kinds of PTH levels in the hemodialysis patients, but not in patients with the vascular type of dementia and the bone-joints disorders which renal functins might be responsible for fragmentation of PTHH in blood stream. This results suggested that the measurement of PTH levels needed to examine various kinds ofamino-sequence of PTH levels in keeping normal function of kidney.
A simple and reliable method for the determination of222Rn concentration in natural water using a liquid scintillation counting technique was investigated. Water sample (50ml) containing222Rn was directly mixed into emulsive liquid scintillator (50 ml), followed by the spectrometric measurements by a multichannel pulse height analyzer coupled to a low background liquid scintillation counter. Weak quenching effect due to the increase of water fraction and the ionic constituents did not bother the determination of low-level222Rn concentration because the liquid scintillationspectrometry could easily distinguish the alphaparticle spectrum even in quenched samples. Since the present procedure is not necessary for the correction of the recovery yield of222Rn, the experimental error included is very small in comparison with the widespread extraction method of222Rn with organic solvent. The detection limit of222Rn concentration was estimated to be about 74 mBq/l (triple the standard deviation of background counting) in a fixed counting time of 100 min.
In order to incinerate the emulsive liquid scintillator waste containing32P, 35S and45Ca, application of demulsion by salt out technique for pre-treatment had been experimentally investigated. As the results, it was obtained that about 99% of aqueous content was removed from the liquid waste and their viscosities were being less than 5 cP. Then, more than 95% of radioactivities of the above nuclides were simultaneously removed together with aqueous content, by using 4 M NaCl and 3 M (NH4) 2CO3as salt out reagents for the liquid scintillator wastes containing inorganic labeled compounds such as KH232PO4, H235SO4and45CaCl2, and organic labeled compounds such as32P-ATP and35S-methionine respectively. Still, as other common conditions for demulsion, it was found that suitable factors were mixing time of 2 min and temperature of 40-50°C.