n-Alkanoic acids (C
12-C
36), n-alkanols (C
12-C
36) and n-alkanes (C
15-C
37) were determined for thirteen samples of lake (Lake Haruna), river (Tama River, Houston Ship Channel) and marine (Tokyo Bay, Galveston Bay, Gulf of Mexico) sediments, soils and activated sludges.
In order to estimate the origins of these compounds in the environmental samples, the distribution patterns of the compounds were compared with those for the presumed source organisms. First, the data for these compounds in organisms (algae, bacteria, zooplankton, fishes, insects, fungi and higher plants) which appear in the literature, were divided into three types in terms of their distribution pattern, that is, the L/H ratio, which is the relative ratio of lower molecular weight compounds (Σ (≤C
20)) to higher molecular weight compounds (Σ (≥C
20)) (A : 2≤L/H; AB : 2>L/H>1/2; B : 1/2≥L/H). Then the organisms were classified into eight groups by the combination of the L/H ratio types for n-alkanoic acids, n-alkanols and n-alkanes (I : A (for n-alkanoic acids), A (for n-alkanols), A (for n-alkanes); II : A, A, AB; III : A, A, B; IV : A, AB, B; V : A, B, B; VI : AB, B, B; VII : B, B, B; 0 : others). The L/H ratios of these compounds in the organisms mostly follow the order : n-alkanoic acids>n-alkanols>n-alkanes.
Comparison indicated that such compounds in the lake and marine sediments and soils are mostly of terrestrial (higher plants) origin, whereas the compounds in the Tama River sediments are considered to originate from algae and/or bacteria. The compounds in the sample from the Houston Ship Channel are strongly influenced by petroleum pollution.
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