Numerical estimation for the flash points of emulsi丘ed fuels were made on the basis of an assumption that emulsion is regarded as a conjugate solution consisting of two liquid phases which are partially soluble in each other,Activity coefficients required in this estimation were evaluated by UNIFAC group-contribution method. Using this method,the flash point of emulsified fuels can only be estimated from the literature values. The estimated flash points tend to deviate upwards slightly,but generally agree well with the measured values not only for the higher molar fraction values but also for the lower values where the simple estimation with Raoult’s law is not available・The mean of the deviations of the estimated flash points from the measuτed one were L6℃for whole molar fraction values and2.0。C even for the lower values than O.9.
We have attempted to clarify the fomation mechanism for long-1ived and highly reactive oxygen・centered gas-phase radicals from the combustion smoke of polymethyl methacrylate and polypropylene using the ESR spin-trapPing technique, The combustion smoke was bubble6through benzene without pheny1-N-t-butylnitroれe(PBN)as a spin trap,and then PBN was added to it after a certain delay time・The gas・phase radi¢als from combustion were much longer-lived in the solution in spite of its high reactivity than that from cigarette smoke, In addition,the combustion smoke was trapped with a CC13F solution of PBN at一78℃,and their ESR spectra were observed under elevating temperature.The ESR signal increased remarkably at-30~一40℃,suggesting any possibility for the decomposition of such a meta-stable oxygen・containing compound as a trioxide,and this behavior is different from that of cigarette smoke, From the above results we can suggest that long・1ived and highly reactive oxygen・centered gas-phase radicals should be produced from combustion smoke by the mechanism involving the formation and decomposition of such a meta-stable oxygen-containing compound as a trioxide.
Hypocenters of AE in coal under triaxial compression were determined。AE waveforms,elastic wave velocity and strains were simultaneously detected by 18 PZT and4strain gauges attached to the sample surface. The connfining pressure applied to the sample was20MPa.The sample fractured with fra¢ture planes parallel to the axial stress direction. In the stage when the coal sample approached to the fracture, AE hypocenters concentratea on the fmcture plane and AE swa㎜was formed around the fracture plane,In the formation process of the AE swarm,AE gap was observed prior to fracture.Hypocenter distribution of AE was fracta1, and the fractal dimension of AE distribution decreased rapidly prior to fracture.