The thermochemical data such as boiling point,heat of vaporization and flash point,and kinetic parameter for aliphatic nitrate were measured to evaluate their hazardous properties.
Owing to the greater attractive forces in a liquid increase as the chain becomes longer,resulting in higher boiling points and greater heat of vaporization, Flash point(Tf)is a linear function of boiling point (Tb)as same as alkanes.
The rate equation in isothemal decomposition are 1/2-order and the compenzation effect is found between logarithm of the frequency factor and the activation energy,then the decomposition proceeds with similar reaction mechanism for each nitrate.
Rotary machilles,which is operated over critical,are accelerated up above critical speed after balancing procedure,It is dimcult for evell a skilled operator to judge from vibration Ievel with disturbance and noise during accelerathlg whether a rotor has good balancing enough to pass criUcal speed or not,Therefore,it is desired to develop some monitorillg system to diagnose balancing condition by on line in real-time. Then in order to diagnose balancing condition of a rotor under uncertain variations of vibration level,the monitoring system with prediction mode1(Kalma filter)was developed and installed in personal computer,After considering adequacy of model alld comparing 3 kinds of sensors used this system,the performance of this system was compared with other techniques,111experiment,this monitoring system could diagnose balancing condition of a rotor at about 20 rps whose critical speed was 43 rps,And these performance were higher than other diagnostic techniques based on vibration leve1.Through these investigations,it is clarified that this system using prediction model is capable of inspecting rotor colldition.