This study was carried out to determine the feasibility of purifying milking waste water by using a freeze-concentrating technique that makes use of cold outdoor air. After partially freezing the waste water, the upper layer of ice contains less waste, as the waste is naturally concentrated in the lower unfrozen layer of waste water.
In this study, waste water contained in a vessel (70mm in diameter and 210mm deep) was frozen from the top downwards by blowing cold ambient air horizontally across the water surface in a freezing room.
The results are summarized as follows:
1) As the cold ambient air temperature decreased and the air velocity increased, the freezing rate of the ice layer increased.
2) As the freezing rate increased, the COD concentration in the frozen layer increased and the purifying rate (i. e., COD concentration in the waste water/COD concentration of frozen layer) decreased. This is due to the fact that when the freezing rate is too high, the waste is trapped during the ice crystallization process.
3) As the ice layer grew in thickness, the COD concentration of the newest ice also increased. As a result the COD concentration within the ice layer varied with the location within the ice layer, such that the concentration was lowest at the ice surface and increased with ice depth.
4) Based on the results of this experiment, we were able to develop a predictive equation that relates the COD concentration in the ice layer to the known ambient cold air temperature, the air velocity and the freezing rate.
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