CO
2 sequestration into a deep aquifer is considered one of the most effective methods to solve Global warming problem. In order to realize the geological sequestration of CO
2, we have to develop the method estimating optimum aquifer for CO
2 sequestration and the technique monitoring the behavior of injected CO
2. In this study, for increasing the accuracy of the monitoring survey using electrical and electromagnetic methods, we tried to monitor the behavior of gas, liquid and supercritical CO
2 injected into a sandstone specimen saturated with brine water by measuring resistivity time variations. We made an experimental equipment which can reproduce the high pressure environments same as the underground conditions. A cylindrical sample of Berea sandstone (5cm in diameter and 12cm in length) was used in this experiment. CO
2 of gas, liquid, and supercritical phases was flooded through the sandstone specimen at three different flow rates. We could monitor the movement of CO
2 in the sand stone by the resistivity change and the resistivities increased up to 2 to 3 times. The resistivity changes were monitored for whole period from initial injection time to high saturated time. We estimated the CO
2 replacement ratio using Archie's equation. The CO
2 replacement ratios estimated from resistivity data are nearly equal to those calculated from actual outflow volumes. These results show the high reliability of electrical survey to monitor CO
2 saturation. Additionally, the replacement ratio of liquid and supercritical CO
2 are higher than that of gas CO
2.
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