巻号一覧
26 巻, 6 号
選択された号の論文の5件中1～5を表示しています
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清水 泰, 上野 浩, 高木 終司1975 年 26 巻 6 号 p. 258-263
発行日: 1975/06/01
公開日: 2009/10/30
ジャーナル フリーThe effects of substituents and their positions in pyridine rings on the properties of electroplated nickels were studied. The crystal microstructure, brightness, cracks, and hardness of deposits obtained from Watts bath containing 24×10-3mol/l of saccharin and 10-3 or 10-4 mol/l of pyridine derivatives were explained. When the electrolysis was carried out at a current density of 2 Amp/dm2 in the presence of 10-4mol/l of pyridine derivatives, the following results were obtained: The deposit obtained from the addition of 3-aminopyridine or 3-cyanopyridine was laminar and bright, while that obtained from the addition of 3-methylpyridine, 3-hydroxypyridine, or 3-pyridine carboxylic acid was columnar and dull. The deposit obtained from the addition of 3-pyridine carbaldehyde was granular and semi-bright. The decreasing order of hardness of the deposits obtained from the addition of these 3-substituted pyridines was as follows: cyano>amino>aldehyde>hydroxyl>methyl>carboxyl. The microstructures and brightnesses of the deposits obtained from the addition of 2-, 3-, and 4-aminopyridines were similar one another. The hardness of the deposits obtained from the addition of these aminopyridines was arranged in decreasing order of 2-≥3->4-. No cracks were observed in the deposits mentioned above.抄録全体を表示PDF形式でダウンロード (2838K) -
有田 喜一, 白石 振作, 妹尾 学, 浅原 照三1975 年 26 巻 6 号 p. 264-267
発行日: 1975/06/01
公開日: 2009/10/30
ジャーナル フリーAn investigation was made on the pretreatments for metal finishing with an emulsion obtained by copolymerization of methyl and butyl methacrylates in the presence of an anionic surfactant in an aqueous medium using no ordinary radical initiators. By dipping steel plate, previously coated with phosphate by conversion treatment, into the emulsion, its corrosion resistance and the adhesion of paint film to the steel were improved. The adhesive strength of paint film depended on the kind of emulsions used, especially on the structure of the copolymers. The emulsion of tert-butyl methacrylate copolymer showed much better effects than that of sec- or n-butyl methacrylate copolymer. The difference amoug the three emulsions in metal finighing effect was discussed in terms of the interaction of alkoxyl groups of the copolymer with film-forming components of the coating material.抄録全体を表示PDF形式でダウンロード (521K) -
小西 三郎, 由利 隆英1975 年 26 巻 6 号 p. 268-272
発行日: 1975/06/01
公開日: 2009/10/30
ジャーナル フリーThe effects of chloride on chromium deposits in low concentration CrO3 bath (CrO3 50g/l, H2SO4 0.5g/l, and Na2SiF6 0.5g/l) and its removal were investigated, and the following results were obtained. When copper was a substrate, parts of no plating due to low current density were corroded at 10mg/l of chloride concentration. The area of the corroded parts was enlarged when the chloride concentration was higher, and finally, bright chromium plating was not obtained at a chloride concentration of higher than 30mg/l. However, in bright nickel plating, the covering power was not much decreased up to 100mg/l of chloride concentration and the corrosion of substrate and decrease of brightness were not observed. The chloride in the chromium plating bath was oxidized at anode and removed under ordinary plating conditions, and also it was proved to be removed by the addition of lead peroxide, which would suggest that the chloride mixed in the plating solution was decomposed by the lead peroxide produced at anode during and at a standstill of plating operation so that it was not a very harmful impurity unless its presence was in too much quantity for a while.抄録全体を表示PDF形式でダウンロード (678K) -
発色皮膜の生成・性能に及ぼす電源波形の影響阿部 隆, 内山 利光, 大塚 達雄1975 年 26 巻 6 号 p. 273-277
発行日: 1975/06/01
公開日: 2009/10/30
ジャーナル フリーOxidation of aluminum was carried out with anodizing current of various electric wave forms in 250g/l maleic acid containing 3-4g/l H2SO4.
The coatings obtained with low ripple percent wave forms such as direct current and three-phase full-wave were uniform in thickness and color. The higher ripple percent wave forms were apt to cause the abnormally grown multiple layers and the burning. In the case of single-phase half-wave having the highest ripple percent, the abnormally grown multiple layers were easily formed at the early stage of anodizing and the uniform coating was never obtained.
The deepness of color and coating ratio were affected by H2SO4 concentration and current density, and the color became deeper and the coating ratio increased with the increase of ripple percentage. The hardness of the uniform coating obtained was in the range of Hv(0.05)521 to 537 which was much higher than Hv(0.05)449 of the hard anodic coating obtained in 0°C 15% H2SO4.抄録全体を表示PDF形式でダウンロード (2771K) -
百瀬 治, 内田 荘祐1975 年 26 巻 6 号 p. 278-282
発行日: 1975/06/01
公開日: 2009/10/30
ジャーナル フリーThe authors investigated the effects of ammonia concentration on gas nitrosulfidizing of iron and steel at 570°C for 120min. in the atmosphere of mixed gases composed of a carrier gas, H2S, and NH3. The amount of nitrosulfidizing (weight increase during this treatment) was lager with the increase of ammonia concentration. The hardness of cross-section obtained at 30-50% of NH3 concentration was similar to that obtained by nitriding treatment. It was confirmed by X-ray diffraction and EPMA that the surface layer obtained at 10% of NH3 concentration was mainly composed of FeS; and it was composed of FeS, Fe1-xS, FeN3, Fe4N, etc. when obtained at 30-50% of NH3 concentration.抄録全体を表示PDF形式でダウンロード (1353K)
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