We selected several 20-27% chromium stainless steels containing 5% or 10%Ni, 1%Mo & 1%Cu, and researched the influence of heatreatment from 700°to 1100°C and the effect of decreasing chromium content on the acid resisting property in such high chromium steels. Also we researched the influence of sigma phase and various treatment upon the acid resisting property. At the same time, we researched on the influence of heat treatment upon the acid resisting property of several austenite stainless steels which were made in Japan and foreign countries.
The corrosion tests were performed in boiling 5% sulphuric acid. The results are as follows:
1) The addition of Nickel to such high chromium steels for improvement of the acid resisting property must be up to 5%. The high chromium steels containing 10%Ni formed the structure of two phase of α and γ, and so the acid resisting property was inferior to that of steels forming the structure of one phase of α or γ only. Also this steel formed sigma phase easily when heat treated from 700° to 900°C and so the acid resisting property woresened remarkably.
2) The lower limit of decreasing the chromium content is 25% in such high chromium steels containing 5%Ni, 1%Mo& 1%Cu as far as the acid resistivity is concerned.
3) Addition of Molybdenum and Copper improved remarkably the acid resisting property but the presence of Molybdenum resulted in the formation of sigma phase at the condition of long time heating at 800°C.
4) Some surface treatment removed the unstability of the acid resisting property of different charge or heat treatment near 700°C on such high chromium steel which substancially has superior acid resisting poperty.
5) The acid resisting property of austenite stainless steels containing both Molybdenum and Copper showed nearly no change by heat treatment. The weight loss by corrosion of steels which did not contain both Molybdenum & Copper or which contain Molybdenum only increased remarkably when heat treated at the carbide precipitating temperature.
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