Metal-rich sludgy sediments were collected in the Seikan Undersea Tunnel between Honshu and Hokkaido, Japan. The sediments can be divided into four types: (1) a black slime precipitated on the wall and in the drainages of the pilot tunnel; (2) a red (or yellowish-red) slime precipitated along with the black slime; (3) a white slime deposited around the abandoned shafts in the pilot tunnel and (4) a brown slime sedimented in the settling tank at Hokkaido-side of the pilot tunnel. The results of X-ray diffraction analysis, elemental analysis and scanning electron microscope (SEM) observation indicate the following characteristics of each slime.
1) The black slime is mostly composed of 10Å manganite (todorokite), which is a major component of oceanic manganese oxide deposits. SEM photographs of the slime show a characteristic morphology: aggregates of manganite microspores, 10-20 gm in diameter. Manganese oxide in the slime is considered to be precipitated from seepage waters of oceanic origine, possibly by a rapid manganese-oxidation reaction associated with microbial activity.
2) The red slime contains Fe and Si as major components, while its X-ray diffractogram exhibits no reflection except for gypsum and brushite. The SEM photographs of the slime show a specific form: flocks of filamentary cells, one by 20-30 gm in size. These data imply that the slime may be a product of a certain sheathed bacteria.
3) The white slime is composed of calcite, aragonite, brucite and an albuminous organic matter. These components are considered to be brought with the seepage waters, which have passed through the abandoned shafts filled up with carbonate-albumin gob.
4) The brown slime is a mixture of dolomite, calcite, quartz, gypsum, hausmannite and some organic matters, containing trace amounts(0.1-0.01%) of heavy metals such as Cu, Zn, Mo and Pb. The sources of these precipitates are estimated to be the three kind of (black, red and white) slimes and plastic rocks carried to the settling tank with drain waters.
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