In order to recognize the chronological transition of the volcanism related to the formation of Kuroko deposits, authors examined the variation of major chemical compositions on the felsic and basaltic volcanic rocks that belonged to pre-/post-Kuroko mineralization at the Hokuroku district in northern Japan. The felsic volcanics are classified, based on field observation, into D1 dacite, D2 dacite, and footwall dacite group. The footwall dacite group is further subdivided into Green dacite, Shako dacite, White rhyolite (D3 dacite) and definite footwall dacite(D4 dacite) in descending order of the stratigraphy.
By the preliminary examination on AL
2O
3-(CaO+Na
2O)-K
2O and K
2O-Na
2O-CaO diagrams, it was suggested that about a half of specimens in the footwall dacite group (35/72) could be reliable to discuss the primary difference in chemical compositions without considering the influence of alteration, and that the various dacite in the footwall dacite group could have different origins from the petrological viewpoint.
Post-Kuroko dacite (Green dacite and D2 dacite) and the dacite (Shako dacite and White rhyolite) formed contemporaneously with Kuroko deposits are clearly separated by the AL
2O
3-SiO
2 diagram; the former is plotted in the low Al and slightly high Si domain, and the latter is plotted in the opposite side. On the other hand, D4 dacite (pre-Kuroko activity) and D1 dacite (later in the post-Kuroko volcanism) are dispersed between former two domains. However, they can be clearly separated by CaO-TiO
2 diagram; the D1 group dacite is represented in the high CaO and high TiO
2 domain.
Authors investigated the chronological transition in mean values of major elements by rock type. Data in pre-Kuroko dacite show constant AL
2O
3 and SiO
2 contents. However, the contemporaneous dacite (White rhyolite, except for Shako dacite) is characterized by low MgO/(MgO+FeO
*) and high Na
2O+K
2O value. On the contrary, post-Kuroko dacite (Green dacite and D2 dacite) is characterized by high SiO
2 and low AL
2O
3 contents and high MgO/(MgO+FeO
*) value. Felsic volcanic rocks in the hanging-wall, such as T2 tuff, Porphyry, Granitoid and D1 dacite, show constant AL
2O
3 value with slightly ascending SiO
2 value and slightly descending MgO/(MgO+FeO
*) value from bottom to top stratigraphically. Those indicate that there were two volcanic cycles, and that the Kuroko mineralization took place related to more differentiated magma at the end of the first volcanic cycle, and then another felsic volcanism commenced immediately after Kuroko mineralization.
Basaltic rocks are called B3 (pre-Kuroko), B2-b (just above Kuroko horizon), B2-a (early in the hanging-wall rock units) and B1 (later in the units) basalt respectively in ascending order. It is recognized that TiO
2 contents gradually decrease from B3 (high Ti contents) via B2-b(middle Ti) to B2-a basalts (low Ti), and that TiO
2 contents become high in B1 (high Ti) again on the TiO
2 -SiO
2 diagram. This suggests that B3 basalt would be deeper origin and that the magma chamber would have gradually become shallower until the period of post-Kuroko activity.
Both felsic and basaltic volcanic rocks indicate that the magma chamber changed from deeper level at the pre-Kuroko stage to shallower level at the post-Kuroko volcanism. It appears from the above that the Kuroko mineralization was caused at the transitional period of volcanism that had changed from deeper to shallower origin.
抄録全体を表示