The equilibrium in the reduction of solid ferrous sulphide by hydrogen gas has been studied with the aid of, .a dynamical method as previously reported. The effect of temperature upon the equilibrium constant and the free energy change in the reaction within the, range 775-872°C has been determined. The experimental data are summarized by the equations as follows: FeS (β) +H
2=Fe (β) +H
2S; logKp=- 3098/T+0.141ΔF°=14170-0.645T
By combining the equations here -determihed with the known' ones of hydrogen sulphide, the following equations have been obtained with regard to the dissociation pressure of solid ferrous sulphide.
2FeS (β) =2Fe (β) +S
2; logP
S2=-15582/T+5.382ΔF°=71272-24.917T
And also by combining the values here obtained with theexisting ones, the following therm. odynanile values in relation, to the forniaion of solid ferrous sulphide have been. calculated. Fe (α) +S (γ) = FeS (α);ΔH298.1=-22608 cal ΔF°298.1=-23110 cal
抄録全体を表示