The effects of impurities on the morphology of zinc electro-deposition from acidic zinc sulfate solution (Zn
2+60g/
l, H
2SO
4150g/
l) were observed with a scanning electron microscope and an optical microscope. The results were summarized as follows:
1) Zinc deposits from the pure electrolyte appear as a mixture of hexagonal crystals which have grown with various orientations.
2) The presence of impurities affects the surface structures of zinc deposits. From the effects on the above-mentioned structures, impurities are considered to be classified into following four types:
(a) lst groups: In, Cu, Co. Addition of 10mg/
l In, Cu and Co to this electrolyte do not have influence on the zinc deposition. Namely, in these cases, microstructures are almost the same as that of pure zinc deposit.
(b) 2nd group: Ni, As, Cd, Pb. With the addition of 10mg/
l Ni, As, Cd and Pb, the crystal growth of zinc has been suppressed and fine crystallites are obtained.
(c) 3rd group: Hg, Ag, Ga. The presence of 10mg/
l Hg, Ag and Ga gave a striped zinc deposit of bright crystals.
(d) 4th group: Ge, Sb, Te, Sn, Tl.
Additions of these impurities affect remarkably the structure of zinc deposits and in each case, zinc crystals have characteristic types respectively.
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