Recent studies of Fe-K edge XANES (X-ray Absorption Near Edge Structure) spectrometry on Fe
3+/ΣFe ratio of volcanic glasses are reviewed. Calibration curves relating the pre-edge feature of X-ray absorption spectrum of Fe at ~7111–7116 eV and Fe
3+/ΣFe ratio of silicate glass are established using synthetic silicate glasses of various compositions, which Fe
3+/ΣFe ratios are determined chiefly by Mössbauer spectroscopy. The calibration curves enable us non-destructive, high-precision analysis of Fe
3+/ΣFe ratio of silicate glass with spatial resolution of <10 µm and relatively short measuring time. Fe
3+/ΣFe ratio determined by the method is largely consistent with those determined by wet chemistry and Mössbauer spectroscopy. The method is applied to volcanic glasses (tiny melt inclusions in phenocryst minerals and quenched groundmass glasses) to quantitatively determine their Fe
3+/ΣFe ratios. The results are used to investigate the effect of shallow magmatic processes (degassing and crystallization) on fO
2 of magma, the redox states of primitive melts from various tectonic settings (mid-ocean ridge, hotspot (Hawaii), arc and back arc basin) and the relations between the redox state and other geochemical features of the source mantle.
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