Numerous studies on ethylene and odors in household refrigerators have been presented, whilst few were reported on the airborne carbonyl compounds. The carbonyl compounds in household refrigerators may have possible impacts on human health and food freshness, because some of them are known to cause adverse health effects and to inhibit enzyme activity in vegetables. In this study, authors have attempted to determine the concentrations of carbonyl compounds in air of domestic refrigerators by using a 2,4-dinitrophenylhydrazibe(DNPH)-active sampling-High Performance Liquid Chromatography(HPLC) system. Air concentrations of six carbonyls, including formaldehyde, acetaldehyde, acetone, acrolein, propionaldehyde and butyladehyde, were determined for practically occupied refrigerator and vegetable rooms (
n = 15). The higher level was found in the acetaldehyde concentrations ranging from 14 to 150μg/m
3 with a mean of 59μg/m
3, slightly greater than the Indoor Air Guideline in Japan. The air concentrations in refrigerators were then compared with those in indoor air of rooms where the refrigerators were practically placed. The comparison showed emission sources of acetaldehyde, acetone and acrolein might exist inside the refrigerators. To investigate the factors influencing these concentrations, a partitional clustering of 15 rooms were conducted using room volume, frequency of opening the door, temperature, number of occupants and contents (food and beverage) as variables. The cluster analysis showed the air concentrations of acetaldehyde and acrolein in refrigerators were mostly influenced by number of occupants and stored contents.
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