We had already reported silica/starch organic-inorganic hybrid biodegradable materials. In this paper, the materials were plasticized by sorbitol, and for comparison, the materials plasticized by glycerol were also prepared. With the increase in plasticizer content, the dispersion of starch in the materials was improved. Additionally, it is found that the dispersion of starch influenced the mechanical properties of the materials. Compared with the materials plasticized by glycerol, the materials plasticized by sorbitol possessed the characteristics of good mechanical properties and heat resistance. It is thought to be due to molecular structures of sorbitol and glycerol, because plasticizers formed interactions with starch.
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