Nitrogen adsorption isotherms at 77K on non-porous powders, such as γ-Fe
2O
3, A1100 and SM and silicon carbide, SiC(P) have been measured. The application of experimental isotherms to the 3-parametric adsorption equation was compared with that of the BET equation. The applicable relative pressure range of the 3-parametric adsorption equation was compared with that of the BET equation. The applicable relative pressure range of the 3-parametric adsorption equation was wider, from 0.05 to 0.65, than that of the BET equation which was in the range from 0.05 to 0.35. The surface areas, ∑
T obtained from the 3-parametric adsorption equation showed an agreement within 10% with that from the BET equation, ∑
B. Since the straight line in α
s-plots of N
2 adsorption isotherms were found to pass through the origin of the coordinate, the powders were confirmed to have no micropore. The outer plane surface areas, ∑
Tαs and ∑
Bαs, were determined from the slope of the straight line in α
s-plots of the standard isotherm of N
2 on non-porous hydroxylated silica, on the basis of the surface areas by application of the standard isotherm to the 3-parametric adsorption equation and BET equation, respectively. There is a reasonable agreement of ∑
T and ∑
B with ∑
Tαs, and ∑
Bαs, respectively, and therefore it will be difficult to determine which surface areas were the most reasonable. However, the surface areas obtained from the measurement of the particle diameter in use of a photograph of a scanning electron microscope showed better and reasonable agreement with the surface areas from the 3-parametric adsorption equation than that from BET equation. Therefore, the 3-parametric adsorption equation seemed to be more reasonable than the BET equation.
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